Environmentally benign carbonylation reaction: Palladium-catalyzed hydroxycarbonylation of aryl halides and benzyl chloride derivatives in ionic liquid media

Topics in Catalysis

Volumn 29, Issue 3-4, 2004, Pages 163-166

  Mizushima, Eiichiro ^a   Hayashi, Teruyuki ^a   Tanaka, Masato ^a  

^a NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY AIST   (Japan)

Author keywords

Carbonylation; Ionic liquid; Palladium; Recycle

Indexed keywords

EID: 3042801451     PISSN: 10225528     EISSN: None     Source Type: Journal    
DOI: 10.1023/b:toca.0000029798.75155.ff     Document Type: Article

References (20)

1. (a) A. Mullen, in: New Syntheses with Carbon Monoxide, ed. J. Falbe (Springer-Verlag, West Berlin, 1980) p. 294;
2. (b) M. Beller, in: Applied Homogenous Catalysis with Organometallic Compounds Vol. 1, eds. B. Cornils and W.A. Herrmann (VCH, Weinheim, 1996) p. 148.
3. (a) L. Cassar, M. Foà and A. Gardano, J. Organomet. Chem. 121 (1976) C55;
4. (b) V.V. Grushin and H. Alper, J. Chem. Soc. Chem. Commun. (1992) 611;
5. (c) V.V. Grushin and H. Alper, Organometallics 12 (1993) 1890.
6. (a) F. Monteil and P. Kalck, J. Organomet. Chem., 482 (1994) 45;
7. (b) T. Okano, I. Uchida, T. Nakagaki, H. Konishi and J. Kiji, J. Mol. Catal. 54 (1989) 65;
8. (c) T. Okano, T. Hayashi and J. Kiji, Bull. Chem. Soc. Jpn. 67 (1994) 2339;
9. (d) C.W. Kohlpaintner and M. Beller, J. Mol. Catal A: Chem. 116 (1997) 259;
10. (e) F. Bertoux, E. Monflier, Y. Castanet and A. Mortreux, J. Mol. Catal. A: Chem. 143 (1999) 11.
11. Y. Uozumi and T. Watanabe, J. Org. Chem. 64 (1999) 6921.
12. (a) Y. Chauvin and H. Olivier-Bourbigou, CHEMTECH (1995) September 26;
13. (b) K.R. Seddon, J. Chem. Technol. Biotechnol. 68 (1997) 351;
14. (c) T. Welton, Chem. Rev. 99 (1999) 2071;
15. (d) P. Wasserscheid and W. Keim, Angew. Chem. Int. Ed. 39 (2000) 3772;
16. (f) R. Sheldon, Chem. Commun. (2001) 2399.
17. E. Mizushima, T. Hayashi and M. Tanaka, Green Chem. 3 (2001) 76.
18. V. Calò, P. Giannoccaro, A. Nacci and A. Monopoli, J. Organomet. Chem. 645 (2002) 152.
19. The rate determining step in carbonylation reaction of aromatic iodides is considered to be the nucleophilic attack on an acylmetal intermediate. See [1b].
20. D. Milstein, J. Chem. Soc. Chem, Commun. (1986) 817.