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Volumn 15, Issue 6, 1996, Pages 1630-1636

Heterobimetallic indenyl complexes. Kinetics and mechanism of substitution and exchange reactions of trans-[Cr(CO)3-indenyl-Rh(CO)2] with olefins

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[No Author keywords available]

Indexed keywords


EID: 0001531439     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om950775u     Document Type: Article
Times cited : (39)

References (39)
  • 29
    • 5244249299 scopus 로고    scopus 로고
    • note
    • One of the reviewers suggested an alternative view involving the solvent, which is consistent with the kinetic data and would result in the following equilibria: equation presented The coordinative unsaturation of the metal(s) would justify the intervention of noncoordinating solvents which would be only weakly bound and easily removable by the attack of the incoming ligand. However, the neglegible solvent effect (see Table 3) suggests that specific interactions between solvent molecules and the metals, if any, must be scarcely important.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.