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Volumn 77, Issue 6, 2004, Pages 1201-1207

Oxidation of ethanol induced by simple polyphenols: Prooxidant property of polyphenols

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; IRON COMPOUNDS; ORGANIC ACIDS; OXIDATION;

EID: 3042573926     PISSN: 00092673     EISSN: None     Source Type: Journal    
DOI: 10.1246/bcsj.77.1201     Document Type: Article
Times cited : (12)

References (64)
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  • 32
    • 3042537287 scopus 로고
    • and Ref. 19b
    • The metal-ion chelator DTPA was used in order to keep iron soluble. In the absence of DTPA, no good reproducibility was obtained. The superiority of DTPA to EDTA as the chelator has been described in Ref. 11a. As for the use of DTPA in Fenton reaction, see, for example: M. Kohno, M. Yamada, K. Mitsuta, Y. Mizuta, and T. Yoshikawa, Bull. Chem. Soc. Jpn., 64, 1477 (1991), and Ref. 19b.
    • (1991) Bull. Chem. Soc. Jpn. , vol.64 , pp. 1477
    • Kohno, M.1    Yamada, M.2    Mitsuta, K.3    Mizuta, Y.4    Yoshikawa, T.5
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    • 3042622854 scopus 로고    scopus 로고
    • note
    • Under argon atmosphere the oxidation takes place slightly, because air was not rigorously excluded. However, the amount of acetaldehyde formed was negligible.
  • 42
    • 0028245381 scopus 로고
    • Academic Press, New York
    • b) H. Kaur and B. Halliwell, "Methods in Enzymology," Academic Press, New York (1994), Vol. 233, pp. 67-83.
    • (1994) Methods in Enzymology , vol.233 , pp. 67-83
    • Kaur, H.1    Halliwell, B.2
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    • Academic Press, New York, and also Ref. 17a
    • In Fenton reaction, regeneration of Fe(II) from Fe(III) has been thought to be effected by HOO® formed in situ, see: R. A. Sheldon and J. K. Kochi, "Metal-Catalyzed Oxidation of Organic Compounds," Academic Press, New York (1981), pp. 350-352, and also Ref. 17a; As for recent arguments on the mechanism of Fenton reaction, see: S. Goldstein and D. Meyerstein, Acc. Chem. Res., 32, 547 (1999); and Y. Mekmouche, S. Ménage, C. Toia-Duboc, M. Fontecave, J.-B. Galey, C. Lebrun, and J. Pécaut, Angew. Chem., Int. Ed., 40, 949 (2001).
    • (1981) Metal-Catalyzed Oxidation of Organic Compounds , pp. 350-352
    • Sheldon, R.A.1    Kochi, J.K.2
  • 49
    • 0032809580 scopus 로고    scopus 로고
    • In Fenton reaction, regeneration of Fe(II) from Fe(III) has been thought to be effected by HOO® formed in situ, see: R. A. Sheldon and J. K. Kochi, "Metal-Catalyzed Oxidation of Organic Compounds," Academic Press, New York (1981), pp. 350-352, and also Ref. 17a; As for recent arguments on the mechanism of Fenton reaction, see: S. Goldstein and D. Meyerstein, Acc. Chem. Res., 32, 547 (1999); and Y. Mekmouche, S. Ménage, C. Toia-Duboc, M. Fontecave, J.-B. Galey, C. Lebrun, and J. Pécaut, Angew. Chem., Int. Ed., 40, 949 (2001).
    • (1999) Acc. Chem. Res. , vol.32 , pp. 547
    • Goldstein, S.1    Meyerstein, D.2
  • 50
    • 0035793683 scopus 로고    scopus 로고
    • In Fenton reaction, regeneration of Fe(II) from Fe(III) has been thought to be effected by HOO® formed in situ, see: R. A. Sheldon and J. K. Kochi, "Metal-Catalyzed Oxidation of Organic Compounds," Academic Press, New York (1981), pp. 350-352, and also Ref. 17a; As for recent arguments on the mechanism of Fenton reaction, see: S. Goldstein and D. Meyerstein, Acc. Chem. Res., 32, 547 (1999); and Y. Mekmouche, S. Ménage, C. Toia-Duboc, M. Fontecave, J.-B. Galey, C. Lebrun, and J. Pécaut, Angew. Chem., Int. Ed., 40, 949 (2001).
    • (2001) Angew. Chem., Int. Ed. , vol.40 , pp. 949
    • Mekmouche, Y.1    Ménage, S.2    Toia-Duboc, C.3    Fontecave, M.4    Galey, J.-B.5    Lebrun, C.6    Pécaut, J.7
  • 54
    • 3042625190 scopus 로고    scopus 로고
    • note
    • 3CHO is produced by the whole consequence of ®OH generation and its capture. In terms of ®OH capture by phenolic compounds, a preliminary study has shown that electron-withdrawing substituents tend to decrease its ability.
  • 57
    • 0027573909 scopus 로고
    • For kinetic studies of air oxidation of pyrogallol, see: C. J. Doona and K. Kustin, Int. J. Chem. Kinet., 25, 239 (1993); For the evolution of CO in Scheme 5, see: J. Biochem., 69, 231 (1971).
    • (1993) Int. J. Chem. Kinet. , vol.25 , pp. 239
    • Doona, C.J.1    Kustin, K.2
  • 58
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    • For kinetic studies of air oxidation of pyrogallol, see: C. J. Doona and K. Kustin, Int. J. Chem. Kinet., 25, 239 (1993); For the evolution of CO in Scheme 5, see: J. Biochem., 69, 231 (1971).
    • (1971) J. Biochem. , vol.69 , pp. 231


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