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For Xantphos studies see: (a) Guari, Y.; van Strijdonck, G. P. F.; Boele, M. D. K.; Reek, J. N. H.; Kamer, P. C. J.; van Leeuwen, P. W. N. M. Chem. Eur. J. 2001, 7, 475.
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30344474153
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note
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2 appears green if there is a small amount of palladium black present.
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30
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0000488020
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Hayashi, T.; Konishi, M.; Kobori, Y.; Kumada, M.; Higuchi, T.; Hirotsu, K. J. Am. Chem, Soc. 1984, 106, 158.
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33
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30344467399
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note
-
This is most likely the complex formed; however, attempts to isolate and purify this complex have not been successful.
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-
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34
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2342455028
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2 (in this case, it is diethylphosphines instead of diphenylphosphines on the xanthene backbone): Raebiger, J. W.; Miedaner, A.; Curtis, C. J.; Miller, S. M.; Anderson, O. P.; DuBois, D. L. J. Am. Chem. Soc. 2004, 126, 5502.
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35
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30344450244
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See Supporting Information for NMR spectra
-
See Supporting Information for NMR spectra.
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36
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30344472279
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note
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Toluene was used to make a stock solution of Xantphos so that a more accurate amount of Xantphos could be injected into the reaction vessel. Toluene was used rather than 1,4-dioxane due to solubility problems.
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37
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