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Volumn 25, Issue 1, 2006, Pages 191-196

Nucleophilic attack on carbonyl ligands in a cyclooctatetraene (COT)-coordinated pentacarbonyl diiron complex. Isolation and transformation of the diiron bridging alkoxycarbyne complexes [Fe2{μ-COC 2H5}(COAr)(CO)33(η8- C8H8)]

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC HYDROCARBONS; COMPLEXATION; MOLECULAR STRUCTURE; THERMODYNAMICS; X RAY DIFFRACTION;

EID: 30344450076     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0580452     Document Type: Article
Times cited : (5)

References (34)
  • 6
    • 0003466026 scopus 로고
    • Springer-Verlag: Berlin; Organotitanium Compounds, Part 5, and referencs therein
    • (a) Gmelin Handbook of Inorganic Chemistry; Springer-Verlag: Berlin, 1990; Organotitanium Compounds, Part 5, pp 25-29, and referencs therein.
    • (1990) Gmelin Handbook of Inorganic Chemistry , pp. 25-29
  • 28
    • 0037170010 scopus 로고    scopus 로고
    • According to the properties of di- or polymetal bridging carbene complexes, the intermediates (a) and (b) could be converted to each other, i.e., the monometal carbene ligand and dimetal bridging carbene ligand can be converted to each other, accompanied by a conversion between the terminal CO group and the bridging CO group. For a detailed review on fluxional metal carbonyls, see: Cotton, F. A. Inorg. Chem. 2002, 41, 643.
    • (2002) Inorg. Chem. , vol.41 , pp. 643
    • Cotton, F.A.1
  • 31
    • 0013129136 scopus 로고
    • Harsh and co-workers reported a similar alkyl migration from oxygen to metal in the dimetal bridging alkoxycarbyne complexes in the thermal decomposition, which is probably via a terminal alkoxycarbyne intermediate. For details see: (a) Fong, R. H.; Hersh, W. H. Organometallics 1985, 4, 1468.
    • (1985) Organometallics , vol.4 , pp. 1468
    • Fong, R.H.1    Hersh, W.H.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.