Novel N-nucleophilic addition to and ring-breaking of coordinated cyclooctatetraene in diiron bridging carbyne complexes

Organometallics

Volumn 21, Issue 22, 2002, Pages 4572-4574

  Zhang, Shu ^a   Xu, Qiang ^b   Sun, Jie ^a   Chen, Jiabi ^b  

^a SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

^b NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY AIST   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; COMPLEXATION; LOW TEMPERATURE EFFECTS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; X RAY DIFFRACTION ANALYSIS;

ADDITION PRODUCTS;

ORGANOMETALLICS;

EID: 0038575357     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om020683m     Document Type: Article

References (17)

1. (a) McDaniel, K. F. In Comprehensive Organometallic Chemistry; Wilkinson, G., Stone, F. G. A., Abel, E. W., Eds.; Pergamon Press: Oxford, New York, 1995; Vol. 12, p 601.
2. (b) Yamamoto, A. J. Organomet. Chem. 2000, 600, 159.
3. (c) Ovchinnikov, M. V.; LeBlanc, E.; Guzei, I. A.; Angelici, R. J. J. Am. Chem. Soc. 2001, 123, 11494.
4. Deganello, G. Transition Metal Complexes of Cyclic Polyolefins; Academic Press: New York, 1979.
5. (a) Fray, G. I.; Saxton, R. G. The Chemistry of Cyclooctatetraene and Its Derivatives; Cambridge University Press: Cambridge, U.K., 1978.
6. (b) Lange, G.; Reimelt, O.; Jessen, L.; Heck, J. Eur. J. Inorg. Chem. 2000, 1941.
7. Chen, J.-B.; Li, D.-S.; Yu, Y.; Jin, Z.-S.; Zhou, Q.-L.; Wei, G.-C. Organometallics 1993, 12, 3885.
8. Fleischer, E. B.; Stone, A. L.; Dewar, R. B. K.; Wright, J. D.; Keller, C. E.; Pettit, R. J. Am. Chem. Soc. 1966, 58, 3158.
9. Bush, R. C.; Angelici, R. J. J. Am. Chem. Soc. 1986, 108, 2735.
10. (a) Angelici, R. J. Acc. Chem. Res. 1995, 28, 52.
11. (b) Bullock, R. M. Comments Inorg. Chem. 1991, 12, 1.
12. w = 0.0479.
13. (a) Liu, Y.-J.; Wang, R.-T.; Sun, J.; Chen, J.-B. Organometallics 2000, 19, 3498.
14. (b) Liu, Y.-J.; Wang, R.-T.; Sun, J.; Chen, J.-B. Organometallics 2000, 19, 3784.
15. Wang, R.-T.; Xu, Q.; Sun, J.; Song, L.-C.; Chen, J.-B. Organometallics 2001, 20, 4092.
16. w = 0.0424.
17. Edwarde, J. D.; Goddard, R.; Knox, S. A. R.; McKinney, R. J.; Stone, F. G. A.; Woodward, P. J. Chem. Soc., Chem. Commun. 1975, 828.