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It is well recognized that copper complexes of tetra-N-substituted cyclam derivatives do not isomerize spontaneously in solution. (See ref 6 and Bucher, C.; Duval, E.; Espinosa, E.; Barbe, J.-M.; Verpeaux, J.-N.; Amatore, C.; Guilard, R. Eur. J. Inorg. Chem. 2001, 1077).
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2942742699
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The gold cavity microelectrode was obtained from the Cavity Microelectrode Users Network, CNRS, France (http://www.glvt-cnrs.fr/lecso/ anglais/acceuil.htm).
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