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2c and 10 (R = n-Bu) are present in 3% and 6%, respectively. Flash chromatography on silica with hexane as the eluent affords pure 1,5-di-n-buty1-9,10-diphenylphenanthrene 2 (R = n-Bu, 134 mg) in 84% yield as a white solid (mp 79-80°C).
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22
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4b to be very effective in the annulation reaction of o-iodobiphenyl with diphenylacetylene.
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23
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0043229335
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13C NMR) are in agreement with structures 3 and 4.
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