Electronic structure control of the nucleophilicity of transition metal-thiolate complexes: An experimental and theoretical study

Journal of the American Chemical Society

Volumn 126, Issue 24, 2004, Pages 7627-7638

  Fox, Derek C ^a   Fiedler, Adam T ^b   Halfen, Heather L ^a   Brunold, Thomas C ^b   Halfen, Jason A ^a  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

^b UNIVERSITY OF WISCONSIN EAU CLAIRE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; CRYSTAL STRUCTURE; ELECTRONIC STRUCTURE; REACTION KINETICS; SYNTHESIS (CHEMICAL);

ELECTRONIC STRUCTURE CONTROL; X-RAY CRYSTAL STRUCTURES;

TRANSITION METAL COMPOUNDS;

ALKYL GROUP; BENZYL BROMIDE; COBALT COMPLEX; ENZYME; IRON COMPLEX; LIGAND; METAL ION; NICKEL COMPLEX; SULFIDE; THIOL DERIVATIVE; TOLUENE DERIVATIVE; TRANSITION ELEMENT; ZINC COMPLEX;

ARTICLE; BINDING AFFINITY; CHEMICAL BOND; COMPLEX FORMATION; CRYSTAL STRUCTURE; DENSITY FUNCTIONAL THEORY; MOLECULAR INTERACTION; REACTION ANALYSIS; STRUCTURE ANALYSIS; X RAY CRYSTALLOGRAPHY;

COMPUTER SIMULATION; CRYSTALLOGRAPHY, X-RAY; ELECTROCHEMISTRY; LIGANDS; METALS; MODELS, MOLECULAR; MODELS, THEORETICAL; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; SULFHYDRYL COMPOUNDS;

EID: 2942635092     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja039419q     Document Type: Article

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