The nature of the chain-length dependence of the propagation rate coefficient and its effect on the kinetics of free-radical polymerization. 1. Small-molecule studies

European Polymer Journal

Volumn 42, Issue 1, 2006, Pages 3-20

  Heuts, Johan P A ^a,c   Russell, Gregory T ^b  

^a UNIVERSITY OF MURCIA   (Spain)

^b UNIVERSITY OF CANTERBURY   (New Zealand)

^c EINDHOVEN UNIVERSITY OF TECHNOLOGY   (Netherlands)

Author keywords

Chain length dependent propagation; Chain length dependent termination; Free radical polymerization; Kinetics; Retardation

Indexed keywords

ACTIVATION ENERGY; DATA ACQUISITION; ELECTROMAGNETIC WAVE PROPAGATION; FREQUENCIES; MOLECULAR DYNAMICS; RATE CONSTANTS;

FREQUENCY FACTOR; RADICAL ACTION; RATE COEFFICIENT; TRANSITION STATE;

FREE RADICAL POLYMERIZATION;

EID: 29144487746     PISSN: 00143057     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.eurpolymj.2005.09.022     Document Type: Review

References (83)

1. K. Matyjaszewski, and T.P. Davis Handbook of radical polymerization 2002 Wiley-Interscience New York
2. M. Buback, M. Egorov, R.G. Gilbert, V. Kaminsky, O.F. Olaj, and G.T. Russell Macromol Chem Phys 203 2002 2570
3. G.T. Russell Aust J Chem 55 2002 399
4. M. Buback, L.H. Garcia-Rubio, R.G. Gilbert, D.H. Napper, J. Guillot, and A.E. Hamielec J Polym Sci, Polym Lett 26 1988 293
5. M. Buback, R.G. Gilbert, G.T. Russell, D.J.T. Hill, G. Moad, and K.F. O'Driscoll J Polym Sci, Polym Chem 30 1992 851
6. R.G. Gilbert Pure Appl Chem 64 1992 1563
7. K.F. O'Driscoll G.C. Eastmond A. Ledwith S. Russo P. Sigwalt Comprehensive polymer science vol. 3 1989 Pergamon Press Oxford 161
8. G.B. Smith, G.T. Russell, and J.P.A. Heuts Macromol Theory Simul 12 2003 299
9. M. Buback, M. Egorov, T. Junkers, and E. Panchenko Macromol Rapid Commun 25 2004 1004
10. M. Buback, T. Junkers, and P. Vana Macromol Rapid Commun 26 2005 796
11. A.A. Gridnev, and S.D. Ittel Chem Rev 101 2001 3611
12. J.P.A. Heuts, G.E. Roberts, and J.D. Biasutti Aust J Chem 55 2002 381
13. C.J. Hawker, A.W. Bosman, and E. Harth Chem Rev 101 2001 3661
14. K. Matyjaszewski, and J. Xia Chem Rev 101 2001 2921
15. M. Kamigaito, T. Ando, and M. Sawamoto Chem Rev 101 2001 3689
16. J. Chiefari, Y.K. Chong, F. Ercole, J. Krstina, J. Jeffery, and T.P.T. Le Macromolecules 31 1998 5559
17. C. Barner-Kowollik, T.P. Davis, J.P.A. Heuts, M.H. Stenzel, P. Vana, and M. Whittaker J Polym Sci, Polym Chem 41 2003 365
18. O.F. Olaj, P. Vana, M. Zoder, A. Kornherr, and G. Zifferer Macromol Rapid Commun 21 2000 913
19. G. Moad, and D.H. Solomon The chemistry of free radical polymerization 1995 Pergamon Oxford
20. G.B. Smith, G.T. Russell, M. Yin, and J.P.A. Heuts Eur Polym J 41 2005 225
21. H. Fischer, and L. Radom Angew Chem Int Ed 40 2001 1349
22. G. Moad, E. Rizzardo, D.H. Solomon, and A.L.J. Beckwith Polym Bull 29 1992 647
23. M. Deady, A.W.H. Mau, G. Moad, and T.H. Spurling Makromol Chem 194 1993 1691
24. A.A. Gridnev, and S.D. Ittel Macromolecules 29 1996 5864
25. R.X.E. Willemse, B.B.P. Staal, A.M. Van Herk, S.C.J. Pierik, and B. Klumperman Macromolecules 36 2003 9797
26. O.F. Olaj, M. Zoder, P. Vana, A. Kornherr, I. Schnöll-Bitai, and G. Zifferer Macromolecules 38 2005 1944
27. J.P.A. Heuts, R.G. Gilbert, and L. Radom Macromolecules 28 1995 8771
28. J.P.A. Heuts, R.G. Gilbert, and L. Radom J Phys Chem 100 1996 18997
29. J.P.A. Heuts K. Matyjaszewski T.P. Davis Handbook of radical polymerization 2002 Wiley-Interscience 1
30. V. Van Speybroeck, K. Van Cauter, B. Coussens, and M. Waroquier Chemphyschem 6 2005 180 189
31. K. Héberger, and H. Fischer Int J Chem Kinet 25 1993 249
32. K. Héberger, and H. Fischer Int J Chem Kinet 25 1993 913
33. T. Zytowski, and H. Fischer J Am Chem Soc 118 1997 437
34. D.V. Avila, K.U. Ingold, J. Lusztyk, W.R. Dolbier, H.-Q. Pan, and M. Muir J Am Chem Soc 116 1994 99
35. H. Fischer, and H. Paul Acc Chem Res 20 1987 200
36. M. Weber, and N.J. Turro J Phys Chem A 107 2003 3326
37. S.N. Batchelor, and H. Fischer J Phys Chem 100 1996 9794
38. M. Buback, R.G. Gilbert, R.A. Hutchinson, B. Klumperman, F.-D. Kuchta, and B.G. Manders Macromol Chem Phys 196 1995 3267
39. S. Beuermann, M. Buback, T.P. Davis, R.G. Gilbert, R.A. Hutchinson, and O.F. Olaj Macromol Chem Phys 198 1997 1545
40. J.M. Asua, S. Beuermann, M. Buback, P. Castignolles, B. Charleux, and R.G. Gilbert Macromol Chem Phys 205 2004 2151
41. S. Beuermann, M. Buback, T.P. Davis, R.G. Gilbert, R.A. Hutchinson, and A. Kajiwara Macromol Chem Phys 201 2000 1355
42. S. Beuermann, M. Buback, T.P. Davis, N. García, R.G. Gilbert, and R.A. Hutchinson Macromol Chem Phys 204 2003 1338
43. O.F. Olaj, I. Bitai, and F. Hinkelmann Makromol Chem 188 1987 1689
44. M.L. Coote, T.P. Davis, and L. Radom Macromolecules 32 1999 5270 5276
45. M.L. Coote, T.P. Davis, and L. Radom Macromolecules 32 1999 2935 2940
46. M.L. Coote, T.P. Davis, and L. Radom J Molec Struct-Theochem 462 1999 91 96
47. A.M. Van Herk Macromol Theory Simul 9 2000 433
48. C.H. Bamford G.C. Eastmond A. Ledwidth S. Russo P. Sigwalt Comprehensive polymer science vol. 3 1989 Pergamon London 219
49. M.L. Coote, and T.P. Davis K. Matyjaszewski T.P. Davis Handbook of radical polymerization 2002 Wiley-Interscience New York 263
50. J.C. Bevington, D.A. Cywar, T.N. Huckerby, R.A. Lyons, E. Senogles, and D.A. Tirrell Eur Polym J 27 1991 603
51. J.C. Bevington, B.F. Bowden, D.A. Cywar, R.A. Lyons, E. Senogles, and D.A. Tirrell Eur Polym J 27 1991 1239
52. J.C. Bevington, R.A. Lyons, and E. Senogles Eur Polym J 28 1992 283
53. R.A. Lyons, and E. Senogles Aust J Chem 47 1994 2201
54. R.A. Lyons, and E. Senogles Aust J Chem 47 1994 2211
55. L.J. Garland, and K.D. Bayes J Phys Chem 94 1990 4941
56. Smith GB, Russell GT, Heuts JPA, in preparation.
57. G.B. Smith, J.P.A. Heuts, and G.T. Russell Macromol Symp 226 2005 133
58. S. Perrier, C. Barner-Kowollik, J.F. Quinn, P. Vana, and T.P. Davis Macromolecules 35 2002 8300
59. P. Vana, T.P. Davis, and C. Barner-Kowollik Macromol Rapid Commun 23 2002 952
60. A. Feldermann, M.H. Stenzel, T.P. Davis, P. Vana, and C. Barner-Kowollik Macromolecules 37 2004 2404
61. A. Theis, A. Feldermann, N. Charton, M.H. Stenzel, T.P. Davis, and C. Barner-Kowollik Macromolecules 38 2005 2595
62. A. Theis, A. Feldermann, N. Charton, T.P. Davis, M.H. Stenzel, and C. Barner-Kowollik Polymer 46 2005 6797
63. A.L.J. Beckwith, V.W. Bowry, and K.U. Ingold J Am Chem Soc 114 1992 4983
64. M.B. Wisnudel, and J.M. Torkelson J Polym Sci B, Polym Phys 34 1996 2999
65. V.W. Bowry, and K.U. Ingold J Am Chem Soc 114 1992 4992
66. S. Beuermann, and M. Buback Prog Polym Sci 27 2002 191
67. E. Takács, S.S. Emmi, and L. Wojnárovits Nucl Instr Meth Phys Res B 151 1999 346
68. E. Takács, and L. Wojnárovits Radiat Phys Chem 47 1996 441
69. E. Takács, and L. Wojnárovits Nucl Instr Meth Phys Res B 131 1997 295
70. P.B. Zetterlund, W.K. Busfield, and I.D. Jenkins Macromolecules 32 1999 8041
71. P.B. Zetterlund, W.K. Busfield, and I.D. Jenkins Macromolecules 35 2002 7232
72. K. Ewing, W.K. Busfield, I.D. Jenkins, and P.B. Zetterlund Polym Int 52 2003 1671
73. J.P.A. Heuts, Sudarko, and R.G. Gilbert Macromol Symp 111 1996 147
74. R.G. Gilbert, and S.C. Smith Theory of unimolecular and recombination reactions 1990 Blackwell Scientific Oxford
75. J.I. Steinfeld, J.S. Francisco, and W.L. Hase Chemical kinetics and dynamics 2nd ed. 1999 Prentice-Hall New Jersey
76. D.A. McQuarrie Statistical mechanics 1976 Harper & Row New York
77. D.M. Huang, M.J. Monteiro, and R.G. Gilbert Macromolecules 31 1998 5175
78. V. Van Speybroeck, D. Van Neck, M. Waroquier, S. Wauters, M. Saeys, and G.B. Marin J Phys Chem A 104 2000 10939
79. J.P.A. Heuts, R.G. Gilbert, and I.A. Maxwell Macromolecules 30 1997 726
80. L.H. Yee, J.P.A. Heuts, and T.P. Davis Macromolecules 34 2001 3581
81. Van Speybroeck V. Private communication.
82. O. Exner, and Z. Friedl Prog Phys Org Chem 19 1993 259 and references therein
83. J.A. Kerr, and M.J. Parsonage Evaluated kinetic data on gas phase reactions 1972 Butterworths London