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29044434438
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13C NMR signals for the C=O groups at δ = 178.1 and 171.2, respectively.
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A pure sample of (23R)-21 could not be obtained; therefore the NOE data was recorded on a mixture enriched in (23R)-21.
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Compound (23R)-27 is an intermediate in the Yoshii synthesis of Tetronomycin (see ref. 5).
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