Formation of indene derivatives from bis(cyclopentadienyl) titanacyclopentadienes with alkyl group migration via carbon-carbon bond cleavage

Journal of the American Chemical Society

Volumn 127, Issue 49, 2005, Pages 17188-17189

  Takahashi, Tamotsu ^a   Kuzuba, Yuichi ^a   Kong, Fanzhi ^a,b   Nakajima, Kiyohiko ^c   Xi, Zhenfeng ^b  

^a HOKKAIDO UNIVERSITY   (Japan)

^b PEKING UNIVERSITY   (China)

^c AICHI UNIVERSITY OF EDUCATION   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYL GROUP; BIS(CYCLOPENTADIENYL)TITANACYCLOPENTADIENE DERIVATIVE; CARBON; CYCLOPENTADIENE DERIVATIVE; INDENE DERIVATIVE; TITANIUM DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; CONFORMATIONAL TRANSITION; CRYSTAL STRUCTURE; DISSOCIATION; ELIMINATION REACTION; HYDROLYSIS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION; REACTION ANALYSIS; REPRODUCIBILITY; STRUCTURE ANALYSIS; SYNTHESIS; TECHNIQUE; TEMPERATURE DEPENDENCE; X RAY ANALYSIS;

EID: 29044438172     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0561789     Document Type: Article

References (13)

1. For general reviews of the C-C cleavage of unstrained organic molecules mediated or catalyzed by transition-metal compounds, see: (a) Takahashi, T.; Kanno, K. Metallocene in Regio- and Stereoselective Synthesis. In Topics in Organometallic Chemistry; Takahashi, T., Ed.; Springer: Berlin, 2005; Vol. 8, p 217.
2. (b) Rybtchinski, B.; Milstein, D. Angew. Chem., Int. Ed. 1999, 38, 870-883.
3. (c) Murakami, M.; Ito, Y. In Activation of Unreactive Bonds and Organic Synthesis; Murai, S., Ed.; Springer: Berlin, 1999; pp 97-129.
4. (d) Crabtree, R. H. Chem. Rev. 1985, 85, 245-269.
5. Tillack, A.; Baumann, W.; Lefeber, O. C.; Spannenberg, A.; Kempe, R.: Rosenthal, U. J. Organomet. Chem. 1996, 520, 187-193.
6. Crowe, W. E.; Vu, A. T. J. Am. Chem. Soc. 1996, 118, 5508-5509.
7. (a) Dzwinniel, T. L.; Etkin, N.; Stryker, J. M. J. Am. Chem. Soc. 1999, 121, 10640-10641.
8. (b) Dzwinniel, T. L.; Stryker, J. M. J. Am. Chem. Soc. 2004, 126, 9184.
9. (a) Xi, Z.; Sato, K.; Gao, Y.; Lu, J.; Takahashi, T. J. Am. Chem. Soc. 2003, 125, 9568-9569.
10. See also: (b) Kempe, R. Angew. Chem., Int. Ed. 2004, 43, 1463-1464.
11. Titanacyclopentadienes 1 were prepared according to the following literature. See: Sato, K.; Nishihara, Y.; Huo, S.; Xi, Z.; Takahashi, T. J. Organomet. Chem. 2001, 633, 18-26.
12. Rosenthal, U.; Lefeber, C.; Arndt, P.; Tillack, A.; Baumann, W.; Kempe, R.; Burlakov, V. V. J. Organomet. Chem. 1995, 503, 221.
13. Mach, K.; Turecek, F.; Antroiusov, H.; Hanus, U. Organometallics 1986, 5, 1215.