An all-inorganic, polyoxometalate-based catechol dioxygenase that exhibits > 100 000 catalytic turnovers

Journal of the American Chemical Society

Volumn 121, Issue 42, 1999, Pages 9831-9842

  Weiner, Heiko ^a   Finke, Richard G ^a  

^a Department of Environmental and Radiological Health Sciences   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC COMPOUND; CARBON; CATECHOL DERIVATIVE; IRON COMPLEX; OXYGENASE; VANADIUM DERIVATIVE;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION; ENZYME KINETICS; ENZYME SUBSTRATE; STOICHIOMETRY; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 0033610466     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja991503b     Document Type: Article

References (14)

1. Lead Reviews of Dioxygenases: (a) Que, L., Jr.; Ho, R. Y. N. Chem. Rev. 1996, 96, 2607.
2. (b) Feig, A. L.; Lippard, S. J. Chem. Rev. 1994, 94, 759.
3. (c) Nozaki, M. Top. Curr. Chem. 1979, 78, 145.
4. (d) Microbial Degradation of Organic Molecules; Gibson, D. T., Ed.; Marcel Dekker: New York, 1984.
5. (e) Que, L., Jr. In Iron Carriers and Iron Proteins; Loehr, T. M., Ed.; VCH: New York, 1989; pp 467-524.
6. (f) Lipscomb, J. D.; Orville, A. M. Met. Ions Biol. Syst. 1992, 28, 243.
7. (g) For a recent, comprehensive review on dioxgenases with 398 references, see: Funabiki, T. In Catalysis by Metal Complexes, Oxygenase and Model Systems; Funabiki, T., Ed.; Kluwer Academic Press: Dordrecht, Holland, 1997; Vol. 19, Chapter 2, p 19-104.
8. (h) Funabiki, T. In Catalysis by Metal Complexes, Oxygenase and Model Systems; Funabiki, T., Ed.; Kluwer Academic Press: Dordrecht, Holland, 1997; Vol. 19, Chapter 3, p 105-155.
9. (i) Nishinaga, A. In Catalysis by Metal Complexes, Oxygenase and Model Systems; Funabiki, T., Ed.; Kluwer Academic Press: Dordrecht, Holland, 1997; Vol. 19, Chapter 4, p 157-194.
10. 2d,e show that the product is mainly simple autoxidation to the benzoquinone: Weller, M. G.; Weser, U. J. Am. Chem. Soc. 1982,104, 3752.
11. (b) Between 7 and 19 turnover of intradiol cleavage: Viswanathan, R.; Palaniandavar, M. J. Chem. Soc., Dalton Trans. 1995, 1259.
12. III thermodynamic sink: Duda, M.; Pascaly, M.; Krebs, B. Chem. Commun. 1997, 835.
13. 2a
14. (e) Up to 8 TTOs of intradiol, extradiol, and quinone products: Funabiki, T.; Mizogughi, A.; Sugimoto, T.; Yoshida, S. Chem. Lett. 1983, 917.