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Jang, H. G.; Cox, D. D.; Que, L., Jr. J. Am. Chem. Soc. 1991, 113, 9200-9204.
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Que Jr., L.3
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(a) Winfield, C. J.; Al-Mahrizy, Z.; Gravestock, M.; Bugg, T. D. H. Perkin 1 2000, 3277-3289.
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8
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2-incorporated, polyoxometalate precatalyst
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2-Incorporated, Polyoxometalate Precatalyst. Inorg. Chem. 2005, 44, 4157-4188.
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Yin, C.-X.1
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9
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26644459172
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Ph.D. Dissertation, University of Oregon, Eugene, OR
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Lyon, D. K. Ph.D. Dissertation, University of Oregon, Eugene, OR, 1990, p 252; see also pp 142-145.
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Lyon, D.K.1
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11
-
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26644454997
-
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note
-
2).
-
-
-
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12
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17244362738
-
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see footnote 45 therein
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Hagen, C. M.; Vieille-Petit, L.; Laurenczy, G.; Süss-Fink, G.; Finke, R. G. Organometallics 2005, 24, 1819-1831, see footnote 45 therein.
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Hagen, C.M.1
Vieille-Petit, L.2
Laurenczy, G.3
Süss-Fink, G.4
Finke, R.G.5
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13
-
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33847090283
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(a) Original work using the pseudoelementary step concept as a kinetic tool in understanding oscillatory reactions: (a) Field, R. J.; Noyes, R. M. Acc. Chem. Res. 1977, 10, 214-221.
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Field, R.J.1
Noyes, R.M.2
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17
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0035095461
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(b) Widegren, J. A.; Aiken, J. D., III; Özkar, S.; Finke, R. G. Chem. Mater. 2001, 13, 312-324.
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Widegren, J.A.1
Aiken III, J.D.2
Özkar, S.3
Finke, R.G.4
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18
-
-
26644473363
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Unpublished results and experiments in progress
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Morris, A. M.; Yin, C.-X.; Finke, R. G. Unpublished results and experiments in progress.
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Morris, A.M.1
Yin, C.-X.2
Finke, R.G.3
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19
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0001188525
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-
2 are quite short, 1.827(4) Å, in comparison to V-O(semiquinone) bond length of 1.975-1.987 Å, showing the variable interactions present between V and catecholate or semiquinone oxygen atoms. (a) Cass, M. E.; Green, D. L.; Buchanan, R. M.; Pierpont, C. G. J. Am. Chem. Soc. 1983, 105, 2680-2686.
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Cass, M.E.1
Green, D.L.2
Buchanan, R.M.3
Pierpont, C.G.4
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20
-
-
26644460149
-
-
note
-
(b) We thank Professor C. G. Pierpont for a discussion and his insights on this point.
-
-
-
-
22
-
-
33845553689
-
-
(d) The classic Rappé-Goddard importance of a spectator oxo ligand also merits mention with respect to Scheme 3: Rappé, A. K.; Goddard, W. A., III. J. Am. Chem. Soc. 1982, 104, 3287-3294.
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Rappé, A.K.1
Goddard III, W.A.2
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23
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0002607321
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Barbaro, P.; Bianchini, C.; Linn, K.; Mealli, C.; Meli, A.; Vizza, F. Inorg. Chim. Acta 1992, 198-200, 31-56.
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Inorg. Chim. Acta
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Barbaro, P.1
Bianchini, C.2
Linn, K.3
Mealli, C.4
Meli, A.5
Vizza, F.6
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24
-
-
0001080403
-
-
2, dissociates into monomer in coordinating solvent as demonstrated by NMR: Buchanan, R. M.; Pierpont, C. G. Inorg. Chem. 1979, 18, 1616-1620.
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Buchanan, R.M.1
Pierpont, C.G.2
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25
-
-
1642401336
-
-
4 also dissociates into monomer upon ligand addition: Liu, C.-M.; Nordlander, E.; Schmeh, D.; Shoemaker, R.; Pierpont, C. G. Inorg. Chem. 2004, 43, 2114-2124.
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Liu, C.-M.1
Nordlander, E.2
Schmeh, D.3
Shoemaker, R.4
Pierpont, C.G.5
-
28
-
-
26644431756
-
-
note
-
Enzymic half-site reactivity is observed in proteins composed of n identical subunits but which react with a substrate or an inhibitor with only n/2 subunits saturated with that ligand. Binding of the ligand to one site typically induces a conformational change of the second binding site, thereby rendering the second site inactive.
-
-
-
-
29
-
-
0015247054
-
-
(a) Levitzki, A.; Stallcup, W. B.; Koshland, D. E., Jr. Biochemistry 1971, 10, 3371-3378.
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Levitzki, A.1
Stallcup, W.B.2
Koshland Jr., D.E.3
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30
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0016041447
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(b) Seydoux, F.; Malhotra, O. P.; Bernhard, S. A. CRC Crit. Rev. Biochem. 1974, 2, 227-257.
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Seydoux, F.1
Malhotra, O.P.2
Bernhard, S.A.3
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31
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0034599291
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20a (a) Bencini, A.; Bill, E.; Mariotti, F.; Totti, F.; Scozzafava, A.; Vargas, A. Inorg. Chem. 2000, 39, 1418-1425.
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Bencini, A.1
Bill, E.2
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Totti, F.4
Scozzafava, A.5
Vargas, A.6
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32
-
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0001067268
-
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2 site of DTBC are commonly proposed in the literature: Cox, D. D.; Que, L., Jr. J. Am. Chem. Soc. 1988, 110, 8085-8092.
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Cox, D.D.1
Que Jr., L.2
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35
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0034732507
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(e) Yamahara, R.; Ogo, S.; Watanabe, Y.; Funabiki, T.; Jitsukawa, K.; Masuda, H.; Einaga, H. Inorg. Chim. Acta 2000, 300-302, 587-596.
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Yamahara, R.1
Ogo, S.2
Watanabe, Y.3
Funabiki, T.4
Jitsukawa, K.5
Masuda, H.6
Einaga, H.7
-
36
-
-
26644475137
-
-
note
-
2 plus bound catecholate benefited from several discussions with Prof. C. Pierpont; it is our pleasure to acknowledge and thank him for those insightful discussions.
-
-
-
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38
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0003487210
-
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University Science Books: Mill Valley, CA
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(b) Collman, J. P.; Hegedus, L. S.; Norton, J. R.; Finke, R. G. Principles and Applications of Organotransition Metal Chemistry; University Science Books: Mill Valley, CA, 1987; pp 192-197.
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Collman, J.P.1
Hegedus, L.S.2
Norton, J.R.3
Finke, R.G.4
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41
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1542378704
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(b) Costas, M.; Mehn, M. P.; Jensen, M. P.; Que, L., Jr. Chem. Rev. 2004, 104, 939-986.
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Costas, M.1
Mehn, M.P.2
Jensen, M.P.3
Que Jr., L.4
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42
-
-
0001076486
-
-
2 labeling prediction that will reveal whether O-scrambling occurs with the initial "spectator oxo" present in the catalyst, an experiment which can, then, be compared to literature precedent [(a) White, L. S.; Nilsson, P. V.; Pignolet, L. H.; Que, L., Jr. J. Am. Chem. Soc. 1984, 106, 8312-8313.
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White, L.S.1
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Que Jr., L.4
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43
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0001471280
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(b) Funabiki, T.; Mizoguchi. A.; Sugimoto, T.; Tada, S.; Mitsuji, T.; Sakamoto, H.; Yoshida, S. J. Am. Chem. Soc. 1986, 108, 2921-2932.] This experiment is under investigation.
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Funabiki, T.1
Mizoguchi, A.2
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Tada, S.4
Mitsuji, T.5
Sakamoto, H.6
Yoshida, S.7
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44
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33751385370
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(a) Dei, A.; Gatteschi, D.; Pardi, L. Inorg. Chem. 1993, 32, 1389-1395.
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Dei, A.1
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45
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0034605881
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(b) Jo, D.-H.; Que, L., Jr. Angew. Chem., Int. Ed. 2000, 39, 4284-4287.
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Jo, D.-H.1
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0034813032
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(c) Lin, G.; Reid, G.; Bugg, T. D. H. J. Am. Chem. Soc. 2001, 123, 5030-5039.
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Lin, G.1
Reid, G.2
Bugg, T.D.H.3
-
47
-
-
26644443820
-
-
note
-
40-catalyzed DTBC oxygenation to primarily the autoxidation product 6 in 27-44% yield.
-
-
-
-
48
-
-
0002687404
-
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(a) Funabiki, T.; Mizoguchi, A.; Sugimoto, T.; Yoshida, S. Chem. Lett. 1983, 917-920.
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Funabiki, T.1
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Sugimoto, T.3
Yoshida, S.4
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49
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0001471280
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(b) Funabiki, T.; Mizoguchi, A.; Sugimoto, T.; Tada, S.; Mitsuji, T.; Sakamoto, H.; Yoshida, S. J. Am. Chem. Soc. 1986, 108, 2921-2932.
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Funabiki, T.1
Mizoguchi, A.2
Sugimoto, T.3
Tada, S.4
Mitsuji, T.5
Sakamoto, H.6
Yoshida, S.7
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50
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-
26644434319
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Funabiki, T., Ed.; Kluwer Academic Publishers: Dordrecht, The Netherlands
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(a) Funabiki, T. In Catalysis by Metal Complexes; Funabiki, T., Ed.; Kluwer Academic Publishers: Dordrecht, The Netherlands, 1997; Vol. 19, pp 80-83.
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Funabiki, T.1
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51
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26644466044
-
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note
-
450.
-
-
-
-
52
-
-
0030788464
-
-
2 to be used for substrate oxidation, there appears to be no known catalytic system that operates as an artificial 'dioxygenase' under mild conditions toward 'difficult' substrates, such as those possessing unactivated primary C-H bonds." Lin, M.; Hogan, T.; Sen, A. J. Am. Chem. Soc. 1997, 119, 6048-6053.
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Lin, M.1
Hogan, T.2
Sen, A.3
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