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2 converged to R1 = 0.1423 (all data), 0.1006 (I > 2σ(I)); wR2 = 0.3135 (all data), 0.2731 (I > 2σ(I)). One molecule of THF was disordered. Atoms Al(2), Si(3), Si(3′), C(7), C(8), C(7′), C(8′), O(7), C(30), and C(32) all had half occupancies. All calculations were performed with the SHELXTL-97 package. CCDC-277386 (1) and -277385 (2) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_ request/cif.
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28044458490
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note
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6): C 45.84, H 9.05, N 3.14, Mg 5.45; found: C 45.39, H 8.83, N 3.21, Mg, 5.31. Deviations from calculated values are attributed to the extremely air sensitive and hygroscopic nature of this compound.
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