New N,N-diisopropylcarbamato complexes of ruthenium(II) as catalytic precursors for olefin hydrogenation

European Journal of Inorganic Chemistry

Volumn , Issue 19, 2004, Pages 3938-3945

  Dell'Amico, Daniela Belli ^a   Calderazzo, Fausto ^a   Englert, Ulli ^b   Labella, Luca ^a   Marchetti, Fabio ^a   Specos, Monica ^a  

^a UNIVERSITY OF PISA   (Italy)

^b RWTH AACHEN UNIVERSITY   (Germany)

Author keywords

Hydrogenation; N,N Dialkylcarbamato complexes; Ruthenium

Indexed keywords

ATMOSPHERIC PRESSURE; CHLORINE COMPOUNDS; HYDROGENATION; SYNTHESIS (CHEMICAL);

1-OCTENE; CARBAMATO LIGANDS; CATALYTIC HYDROGENATION; CATALYTIC PRECURSORS; DIHYDROGEN; DINUCLEAR; N,N-DIALKYLCARBAMATO COMPLEX; OLEFIN HYDROGENATION;

RUTHENIUM COMPOUNDS;

(N,N DIISOPROPYLCARBAMATO)RUTHENIUM COMPLEX; 1 OCTENE; 2 PROPANOL; ALKENE; BRIDGED COMPOUND; CARBAMIC ACID DERIVATIVE; CHLORIDE; RUTHENIUM COMPLEX; UNCLASSIFIED DRUG;

ARTICLE; ATMOSPHERIC PRESSURE; CATALYSIS; HYDROGENATION; PRECURSOR; REACTION ANALYSIS; ROOM TEMPERATURE; SYNTHESIS;

EID: 6344277900     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejic.200400014     Document Type: Article

References (57)

1. [1a] Comprehensive Coordination Chemistry, vol. 4 (Eds.: G. Wilkinson, R. D. Gillard, J. A. McCleverty), Pergamon Press, Oxford, 1988.
2. [1b] Comprehensive Coordination Chemistry II, vol. 4 (Eds.: J. A. McCleverty, T. J. Meyer), Elsevier Ltd., Oxford, 2004.
3. [1c] Comprehensive Organometallic Chemistry II, vol. 7 (Eds.: E. W. Abel, F. G. A. Stone, G. Wilkinson), Pergamon Press, Oxford, 1995.
4. [1d] D. Rose, J. D. Gilbert, R. P. Richardson, G. Wilkinson, J. Chem. Soc. 1969, 2610-2615, and references cited therein.
5. [2a] R. W. Mitchell, A. Spencer, G. Wilkinson, J. Chem. Soc., Dalton Trans. 1973, 846-854.
6. [2b] S. D. Robinson, M. F. Uttley, J. Chem. Soc., Dalton Trans. 1973, 1912-1920.
7. [2c] A. Dobson, S. D. Robinson, M. F. Uttley, J. Chem. Soc., Dalton Trans. 1975, 370-377.
8. [2d] C. J. Creswell, A. Dobson, D. S. Moore, S. D. Robinson, Inorg. Chem. 1979, 18, 2055-2059.
9. [2e] M. Rotem, Z. Stein, Y. Shvo, J. Organomet. Chem. 1990, 387, 95-101.
10. [2f] T. Arligule, B. Chaudret, G. Chung, F. Dahan, Organometallics 1991, 10, 2973-2977.
11. [2g] P. Frediani, C. Faggi, A. Salvini, M. Bianchi, F. Piacenti, Inorg. Chim. Acta 1998, 272, 141-149.
12. [2h] G. Sbrana, G. Braca, E. Giannetti, J. Chem. Soc., Dalton Trans. 1976, 1847-1852.
13. [3a] D. Belli Dell'Amico, F. Calderazzo, L. Labella, F. Marchetti, J. Organomet. Chem. 2000, 596, 144-151.
14. [3b] D. Belli Dell' Amico, F. Calderazzo, A. Grazzini, L. Labella, F. Marchetti, Inorg. Chim. Acta 2002, 334, 411-418.
15. [3c] D. Belli Dell'Amico, F. Calderazzo, L. Labella, F. Marchetti, E. Sbrana, J. Organomet. Chem. 2002, 651, 52-59.
16. [4a] T. V. Ashworth, M. Nolte, E. Singleton, J. Organomet. Chem. 1976, 121, C57-C60.
17. [4b] T. V. Ashworth, M. J. Nolte, E. Singleton, S. Afr. J. Chem. 1978, 31, 149-152.
18. [4c] T. Tsuda, M. Shiro, Organometallics 1999, 18, 2741-2743.
19. [5a] A. Belforte, D. Belli Dell'Amico, F. Calderazzo, U. Giurlani, L. Labella, Gazz. Chim. Ital 1993, 123, 119-127.
20. [5b] D. Belli Dell'Amico, F. Calderazzo, L. Labella, F. Marchelli, G. Pampaloni, Chem. Rev. 2003, 103, 3857-3897.
21. [6a] P. Haynes, L. H. Slaugh, J. F. Kohnle, Tetrahedron Lett. 1970, 365-368.
22. [6b] S. J. La Placa, J. A. Ibers, Inorg. Chem. 1965, 4, 778-783.
23. [7a] K. Mashima, T. Nakamura, Y. Matsuo, K. Tani, J. Organomet. Chem. 2000, 607, 51-56.
24. [7b] D. Huang, K. Folting, K. G. Caulton, Inorg. Chem. 1996, 35, 7035-7040.
25. [8a] T. Ohta, Y. Tonomura, K. Nozaki, H. Takaya, K. Mashima, Organometallics 1996, 15, 1521-1523.
26. [8b] K. S. MacFarlane, I. S. Thorburn, P. W. Cyr, D. E. K.-Y. Chau, S. J. Rettig, B. R. James, Inorg. Chim. Acta 1998, 270, 130-144.
27. [9a] A. C. Skapski, P. G. H. Troughton, J. Chem. Soc., Chem. Commun. 1968, 1230-1231.
28. [9b] A. C. Skapski, F. A. Stephens, J. Chem. Soc., Dalton Trans. 1974, 390-395.
29. [9c] V. V. Mainz, R. A. Andersen, Organometallics 1984, 3, 675-678.
30. [10a] P. W. Armit, A. S. F. Boyd T. A. Stephenson, J. Chem. Soc., Dalton Trans. 1975, 1663-1672.
31. [10b] P. R. Hoffman, K. G. Caulton, J. Am. Chem. Soc. 1975, 97, 4221-4228.
32. J. Halpern, J. F. Harrod, B. R. James, J. Am. Chem. Soc. 1966, 88, 5150-5155.
33. [12a] S. Komiya, A. Yamamoto, S. Ikeda, J. Organomet. Chem. 1972, 42, C65-C66.
34. [12b] S. Komiya, A. Yamamoto, Bull. Chem. Soc. Jpn. 1976, 49, 2553-2559.
35. T. V. Ashworth, E. Singleton, J. Organomet. Chem. 1976, 117, C113-C115.
36. G. G. A. Balavoine, T. Boyer, Organometallics 1992, 11, 456-459.
37. B. de Klerk-Engels, J. G. P. Delis, K. Vrieze, K. Goubitz, J. Fraanje, Organometallics 1994, 13, 3269-3278.
38. P. S. Hallman, B. R. McGarvey, G. Wilkinson, J. Chem. Soc. A 1968, 3143-3150.
39. [17a] D. E. Linn, J. Halpern, J. Am. Chem. Soc. 1987, 109, 2969-2974.
40. [17b] L. S. Van Der Sluys, G. J. Kubas, K. G. Caulton, Organometallics 1991, 10, 1033-1038.
41. [17c] E. Hoel, M. F. Hawthorne. Inorg. Synth. 1974, 15, 31-34.
42. [17d] W. H. Knoth, J. Am. Chem. Soc. 1972, 94, 104-109.
43. [18a] T. V. Ashworth, E. Singleton, J. Chem. Soc., Chem. Commun. 1976, 705-706.
44. [18b] R. H. Crabtree, D. G. Hamilton, J. Am. Chem. Soc. 1986, 108, 3124-3125.
45. [18c] R. H. Crabtree, D. G. Hamilton, J. Am. Chem. Soc. 1988, 110, 4126-4133.
46. [19a] R. O. Harris, N. K. Hota, L. Sadavoy, M. C. Yuen, J. Organomet. Chem. 1973, 54, 259-264.
47. [19b] T. Ito, S. Kitazume, A. Yamamoto, S. Ikeda, J. Am. Chem. Soc. 1970, 92, 3011-3016.
48. 31P NMR spectroscopy).
49. [20a] K. Abdur-Rashid, A. J. Lough, R. H. Morris, Organometallics 2000, 19, 2655-2657.
50. [20b] C. P. Casey, S. W. Singer, D. R. Powell, R. K. Hayashi, M. Kavana, J. Am. Chem. Soc. 2001, 123, 1090-1100.
51. [20c] K. Abdur-Rashid, S. E. Clapham, A. Hadzovic, J. N. Harvey, A. J. Lough, R. H. Morris, J. Am. Chem. Soc. 2002, 124, 15104-15118.
52. P. S. Hallman, T. A. Stephenson, G. Wilkinson, Inorg. Synth. 1970, 12, 237-240.
53. F. L'Eplattenier, F. Calderazzo, Inorg. Chem. 1968, 7, 1290-1293.
54. A. Pifferi, L. Barba, DARX2000 V1.0.3, CNR-IC, Montelibretti, Roma, Italy, 2000.
55. ENRAF-Nonius SDP V5.0, Delft, The Netherlands, 1989.
56. G. M. Sheldrick, SHELX-97, Programs for Crystal Structure Analysis (Release 97-2), University of Göttingen, Germany, 1998.
57. G. M. Sheldrick, SHELXTL-Plus, Rel. 5.03, Bruker AXS, Madison, Wisconsin, USA, 1995.