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We shall ignore the possibility that some of those electrons reside on the P-cluster.
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27844514946
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note
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It is even less likely for a bridge between Fe and Mo.
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27844468901
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note
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For bridging species, eq 2 must be summed over interacting Fe.
-
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47
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27844500420
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note
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We think an "accidental" equality of the products when the individual factors are different to be even more unlikely.
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48
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27844451286
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note
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We further suggest below that the two intermediates represent different LT kinetic states.
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27844537651
-
-
note
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4 bound or convert to intermediate- or low-spin.
-
-
-
-
61
-
-
27844549631
-
-
note
-
Such a valency assessment has no consequences for the magnetism of a "typical" organometallic center, with S = 0 even-electron metal ions. However, in principle it has experimentally observable consequences for the magnetic properties of a metal cluster comprised of spin-coupled high-spin, open-shell Fe(II/III) ions: the two electrons provided by the cofactor to the C-Fe σ-bonds of the ferracyclopropane no longer participate in the cluster spin system, and the consequence to the ion would be the same (magnetically) as if complex formation had driven it to intermediate spin.
-
-
-
-
62
-
-
27844557191
-
-
note
-
The same may not be true for bound allyl alcohol.
-
-
-
|