A general thiolation of magnesium organometallics using tetramethylthiuram disulfide

Synlett

Volumn , Issue 17, 2005, Pages 2691-2693

  Krasovskiy, Arkady ^a   Gavryushin, Andrey ^a   Knochel, Paul ^a  

^a UNIVERSITY OF MUNICH   (Germany)

Author keywords

Chirality; Grignard reactions; Lithium chloride; Sulfur; Tetramethylthiuram disulfide

Indexed keywords

BROMINE DERIVATIVE; DITHIOCARBAMIC ACID DERIVATIVE; LITHIUM DERIVATIVE; MAGNESIUM DERIVATIVE; ORGANOMETALLIC COMPOUND; PRASEODYMIUM COMPLEX; THIOL DERIVATIVE; THIRAM;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL MODIFICATION; CHEMICAL STRUCTURE; COMPLEX FORMATION; GRIGNARD REACTION; THIOLATION;

EID: 27444434617     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2005-917115     Document Type: Article

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25. 2Si derivative by treatment with ICl.
26. We have treated also different alkyl magnesium compounds with TMTD in the presence of LiCl and have obtained corresponding thioderivates in excellent yields.
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