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One of reviewers has raised an another possibility that methanol activated on the Lewis acidic metal center reacts with epoxide to give the ring-opened product. If this is true, the methanol activated would attack the less-hindered β-carbon center of styrene oxide rather than the hindered α-carbon due to the steric hindrance between styrene oxide and the methanol activated on the Lewis acidic metal, resulting in giving mainly the secondary alcohol. However, we observed only the primary alcohol which means that the methanol activated is not a nucleophilic species. Therefore, this possibility can be excluded.
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