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Volumn 26, Issue 9, 2005, Pages 1434-1436

Conversion of epoxides into trans-diols or trans-diol mono-ethers by iron(III) porphyrin complex

Author keywords

Diol mono ethers; Diols; Epoxide ring opening; Iron(III) porphyrin

Indexed keywords


EID: 27344445011     PISSN: 02532964     EISSN: None     Source Type: Journal    
DOI: 10.5012/bkcs.2005.26.9.1434     Document Type: Article
Times cited : (5)

References (24)
  • 17
    • 27344460230 scopus 로고    scopus 로고
    • note
    • 3 in the same time period.
  • 22
    • 27344437845 scopus 로고    scopus 로고
    • note
    • One of reviewers has raised an another possibility that methanol activated on the Lewis acidic metal center reacts with epoxide to give the ring-opened product. If this is true, the methanol activated would attack the less-hindered β-carbon center of styrene oxide rather than the hindered α-carbon due to the steric hindrance between styrene oxide and the methanol activated on the Lewis acidic metal, resulting in giving mainly the secondary alcohol. However, we observed only the primary alcohol which means that the methanol activated is not a nucleophilic species. Therefore, this possibility can be excluded.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.