Instant "base-promoted" generation of Roper's-type Ru(0) complexes Ru(CO)2(PR3)3 from a simple carbonylchlororuthenium(II) precursor

Journal of the American Chemical Society

Volumn 127, Issue 42, 2005, Pages 14554-14555

  Sentets, Stephane ^a   Rodriguez Martinez, Maria Del Carmen ^a   Vendier, Laure ^a   Donnadieu, Bruno ^a   Huc, Vincent ^a   Lugan, Noël ^a   Lavigne, Guy ^a  

^a CNRS   (France)

Author keywords

[No Author keywords available]

Indexed keywords

COBALT COMPLEX; RUTHENIUM COMPLEX;

ARTICLE; CATALYSIS; COMPLEX FORMATION; EXTRACTION; SYNTHESIS; TEMPERATURE;

MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; RUTHENIUM;

EID: 27144436397     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja055066e     Document Type: Article

References (32)

1. Cavit, B. E.; Grundy, K. R.; Roper, W. R. J. Chem. Soc., Chem. Commun. 1972, 60.
2. (a) Clark, G. R.; Hoskins, S. V.; Jones, T. C.; Roper, W. R. J. Chem. Soc., Chem. Commun. 1983, 719.
3. (b) Roper, W. R. J. Organomet. Chem. 1986, 300, 167.
4. (c) Bohle, D. S.; Roper, W. R. Organometallics 1986, 5, 1607.
5. (a) Gaffney, T. R.; Ibers, J. A. Inorg. Chem. 1982, 21, 2851.
6. (b) Alcock, N. W.; Hill, A. F.; Melling, R. P.; Thompsett, A. R. Organometallics 1993, 12, 641.
7. (c) Dewhurst, R. D.; Hill, A. F.; Smith, M. K. Angew. Chem., Int. Ed. 2004, 43, 476.
8. (d) Hill, A. F.; Rae, A. D.; Schultz, M.; Willis, A. C. Organometallics 2004, 23, 81.
9. (e) Hill, A. F.; Schultz, M.; Willis, A. C. Organometallics 2004, 23, 5729.
10. Hiraki, K.; Kira, S.-I.; Kawano, H. Bull. Chem. Soc. Jpn. 1997, 70, 1583.
11. (a) Kakiuchi, F.; Murai, S. Acc. Chem. Res. 2002, 35, 826.
12. (b) Murai, S.; Kakiuchi, F.; Sekine, S.; Tanaka, Y.; Kamatani, A.; Sonoda, M.; Chatani, N. Pure Appl. Chem. 1994, 66, 1527.
13. (c) Kakiuchi, F.; Chatani, N. Adv. Synth. Catal. 2003, 345, 1077 and references therein.
14. Clark, G. R.; Hoskins, S. V.; Jones, T. C.; Roper, W. R. J. Chem. Soc., Chem. Commun. 1983, 719.
15. 2 generally require forcing conditions.
16. (b) Siegl, W. O.; Lapporte, S. J.; Collman, J. P. Inorg. Chem. 1973, 12, 674.
17. (c) Jaunky, P.; Schmalle, H. W.; Blacque, O.; Fox, T.; Berke, H. J. Organomet. Chem. 2004, 689, 801.
18. Ogasawara, M.; Maseras, F.; Gallego-Planas, N.; Kawamura, K.; Ito, K.; Toyota, K.; Streib, W. E.; Komiya, S.; Eisenstein, O.; Caulton, K. G. Organometallics 1997, 16, 1979.
19. (a) Ogasawara, M.; Macgregor, S. A.; Streib, W. E.; Folting, K.; Eisenstein, O.; Caulton, K. G. J. Am. Chem. Soc. 1995, 117, 8869.
20. (b) Ogasawara, M.; Macgregor, S. A.; Streib, W. E.; Folting, K.; Eisenstein, O.; Caulton, K. G. J. Am. Chem. Soc. 1996, 118, 10189.
21. (c) Li, C.; Ogasawara, M.; Nolan, S. P.; Caulton, K. G. Organometallics 1996, 15, 4900.
22. (d) Li, C.; Olivan, M.; Nolan, S. P.; Caulton, K. G. Organometallics 1997, 16, 4223.
23. 10b: (a) Bruce, M. I.; Stone, F. G. A. J. Chem. Soc., A 1967, 1238.
24. (b) Faure, M.; Maurette, L.; Donnadieu, B.; Lavigne, G. Angew. Chem., Int. Ed. 1999, 38, 518.
25. (a) Though the role of ethanol as a reducing agent might have been considered, the reaction can be alternatively performed in acetonitrile, with about the same efficiency;
26. (b) the phosphine needs to be presolubilized in ether because the reaction proceeds much faster than the rate of phosphine solubilization in ethanol.
27. (a) Tanaka, H.; Nagao, H.; Peng, S. M.; Tanaka, K. Organometallics 1992, 11, 1450.
28. (b) Ishida, H.; Tanaka, K.; Moritomo, M.; Tanaka, K. Organometallics 1986, 5, 724.
29. We have verified that tBuOK can be used as an alternate deprotonating agent in the second reaction step.
30. (a) Faure, M.; Saccavini, C.; Lavigne, G. Chem. Commun. 2003, 1578.
31. (b) Faure, M.; Saccavini, C.; Lavigne, G. Inorg. Synth. 2004, 34, 110.
32. Morimoto, T.; Kakiuchi, K. Angew. Chem., Int. Ed. 2004, 43, 5580.