Formation of Di- And Tricarbonylruthenium(O) Species from [RuH2(CO)(PPh3)3] via Decarbonylation of Methyl Benzoates: X-Ray Crystal Structures of [Ru(CO)2(PPh3)3] and [Ru(O2)(CO)2(PPh3)2]

Bulletin of the Chemical Society of Japan

Volumn 70, Issue 7, 1997, Pages 1583-1592

  Hiraki, Katsuma ^a   Kira, Shu Ichi ^a   Kawano, Hiroyuki ^a  

^a NAGASAKI UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

RUTHENIUM COMPLEX; TRICARBOXYLIC ACID;

ARTICLE; CONFORMATIONAL TRANSITION; CRYSTAL STRUCTURE; GEOMETRY; METAL BINDING; MOLECULAR DYNAMICS; STRUCTURE ANALYSIS;

EID: 0030815951     PISSN: 00092673     EISSN: None     Source Type: Journal    
DOI: 10.1246/bcsj.70.1583     Document Type: Article

References (48)

1. a) T. Mitsudo, Y. Nakagawa, K. Watanabe, Y. Hori, H. Misawa, H. Watanabe, and Y. Watanabe, J. Org. Chem., 50, 565 (1985)
2. b) T. Mitsudo, Y. Hori, and Y. Watanabe, J. Organomet. Chem., 334, 157 (1987).
3. T. Naota, H. Taki, M. Mizuno, and S.-I. Murahashi, J. Am. Chem. Soc., 111, 5954 (1989).
4. a) B. M. Trost and R. J. Kulawiec, J. Am. Chem. Soc., 114, 5579 (1992)
5. b) B. M. Trost and A. Indolese, J. Am. Chem. Soc., 115, 4361 (1993).
6. T. Rappert and A. Yamamoto, Organometallics, 13, 4984 (1994), and literatures cited therein.
7. R. H. Grubbs, S. J. Miller, and G. C. Fu, Acc. Chem. Res., 28, 446 (1995), and literatures cited therein.
8. a) S. Murai, F. Kakiuchi, S. Sekine, Y. Tanaka, A. Kamatani, M. Sonoda, and N. Chatani, Nature, 366, 529 (1993)
9. b) F. Kakiuchi, S. Sekine, Y. Tanaka, A. Kamatani, M. Sonoda, N. Chatani, and S. Murai, Bull. Chem. Soc. Jpn., 68, 62 (1995).
10. B. M. Trost, K. Imi, and I. W. Davies, J. Am. Chem. Soc., 117, 5371 (1995).
11. a) F. Kakiuchi, Y. Tanaka, T. Sato, N. Chatani, and S. Murai, Chem. Lett., 1995, 679
12. b) F. Kakiuchi, Y. Yamamoto, N. Chatani, and S. Murai, Chem. Lett., 1995, 681
13. F. Kakiuchi, M. Yamauchi, N. Chatani, and S. Murai, Chem. Lett., 1996, 111.
14. N. Chatani, T. Fukuyama, F. Kakiuchi, and S. Murai, J. Am. Chem. Soc., 118, 493 (1996).
15. a) Y.-G. Lim, Y. H. Kim, and J.-B. Kang, J. Chem. Soc., Chem. Commun., 1994, 2267
16. b) Y.-G. Lim, J.-B. Kang, and Y. H. Kim, J. Chem. Soc., Chem. Commun., 1996, 585.
17. a) K. Hiraki, N. Ochi, T. Kitamura, Y. Sasada, and S. Shinoda, Bull. Chem. Soc. Jpn., 55, 2356 (1982)
18. b) K. Hiraki, N. Ochi, Y. Sasada, H. Hayashida, Y. Fuchita, and S. Yamanaka, J. Chem. Soc., Dalton Trans., 1985, 873.
19. K. Hiraki, Y. Fuchita, H. Kawabata, K. Iwamoto, T. Yoshimura, and H. Kawano, Bull. Chem. Soc. Jpn., 65, 3027 (1992).
20. K. Hiraki, T. Matsunaga, and H. Kawano, Organometallics, 13, 1878 (1994).
21. B. E. Cavit, K. R. Grundy, and W. R. Roper, J. Chem. Soc., Chem. Commun., 1972, 60.
22. R. S. Berry, J. Chem. Phys., 32, 933 (1960).
23. A. G. Orpen, L. Brammer, F. H. Allen, O. Kennard, D. G. Watson, and R. Taylor, J. Chem. Soc., Dalton Trans., 1989, S1.
24. a) M. Ogasawara, S. A. Macgregor, W. E. Streib, K. Folting, O. Eisenstein, and K. G. Caulton, J. Am. Chem. Soc., 117, 8869 (1995)
25. b) M. Ogasawara, S. A. Macgregor, W. E. Streib, K. Folting, O. Eisenstein, and K. G. Caulton, J. Am. Chem. Soc., 118, 10189 (1996).
26. a) M. Ogasawara, F. Maseras, N. Gallego-Planas, W. E. Streib, O. Eisenstein, and K. G. Caulton, Inorg. Chem., 35, 7468 (1996)
27. b) C. Li, M. Ogasawara, S. P. Nolan, and K. G. Caulton, Organometallics, 15, 4900 (1996).
28. T. R. Gaffney and J. A. Ibers, Inorg. Chem., 21, 2851 (1982).
29. J. P. Collman and W. R. Roper, J. Am. Chem. Soc., 87, 4008 (1965).
30. M. Helliwell, J. D. Vessey, and R. J. Mawby, J. Chem. Soc., Dalton Trans., 1994, 1193.
31. J. A. McGinnety, N. C. Payne, and J. A. Ibers, J. Am. Chem. Soc., 91, 6301 (1969).
32. M. J. Bennett and P. B. Donaldson, Inorg. Chem., 16, 1581 (1977).
33. a) W. R. Roper and L. J. Wright, J. Organomet. Chem., 234, C5 (1982)
34. b) G. R. Clark, C. E. L. Headford, K. Marsden, and W. R. Roper, J. Organomet. Chem., 231, 335 (1982).
35. S. Komiya, R. S. Srivastava, A. Yamamoto, and T. Yamamoto, Organometallics, 4, 1504 (1985).
36. W. R. Roper, G. E. Taylor, J. M. Waters, and L. J. Wright, J. Organomet. Chem., 182, C46 (1979).
37. T. Yamamoto, S. Miyashita, Y. Naito, S. Komiya, T. Ito, and A. Yamamoto, Organometallics, 1, 808 (1982).
38. T. Yamamoto, J. Ishizu, T. Kohara, S. Komiya, and A. Yamamoto, J. Am. Chem. Soc., 102, 3758 (1980).
39. M. Sonoda, F. Kakiuchi, A. Kamatani, N. Chatani, and S. Murai, Chem. Lett., 1996, 109.
40. a) J. Powell and B. L. Shaw, J. Chem. Soc. A, 1968, 159
41. b) R. B. King and P. N. Kapoor, Inorg. Chem., 11, 336 (1972)
42. c) S. Cenini, A. Mantovani, A. Fusi, and M. Keubler, Gazz. Chim. Ital., 105, 255 (1975).
43. N. Ahmad, J. J. Levison, S. D. Robinson, and M. F. Uttley, Inorg. Synth., 15, 48 (1974).
44. P. T. Beurskens, G. Admiraal, G. Beurskens, W. P. Bosman, S. Garcia-Granda, R. O. Gould, J. M. M. Smits, and C. Smykalla, "PATTY, The DIRDIF Program System, Technical Report of the Crystallography Laboratory," University of Nijmegen, The Netherlands (1992).
45. P. T. Beurskens, G. Admiraal, G. Beurskens, W. P. Bosman, S. Garcia-Granda, R. O. Gould, J. M. M. Smits, and C. Smykalla, "DIRDIF92, The DIRDIF Program System, Technical Report of the Crystallography Laboratory," University of Nijmegen, The Netherlands (1992).
46. Fan Hai-Fu, "SAPI 91, Structure Analysis Programs with Intelligent Control," Rigaku Corporation, Tokyo, Japan (1991).
47. "International Tables for X-Ray Crystallography," Kynoch Press, Birmingham, England (1974), Vol. IV.
48. "teXsan, Crystal Structure Analysis Package," Molecular Structure Corporation, (1985 and 1992).