Designing molecules for metal-metal electronic communication: Synthesis and molecular structure of the couple of heterobimetallic isomers [η6-(2-ferrocenyl)indene]-Cr(CO)3 and [η6-(3-ferrocenyl)indene]-Cr(CO)3

Organometallics

Volumn 24, Issue 19, 2005, Pages 4691-4694

  Santi, Saverio ^a   Ceccon, Alberto ^a   Bisello, Annalisa ^a   Durante, Christian ^a   Ganis, Paolo ^a   Orian, Laura ^a   Benetollo, Franco ^b   Crociani, Laura ^b  

^a UNIVERSITY OF PADOVA   (Italy)

^b CNR   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

CONFORMATIONS; CRYSTAL STRUCTURE; ELECTRONIC STRUCTURE; ISOMERS; MOLECULAR STRUCTURE; OXIDATION;

CP-INDENE BRIDGING LIGAND; ELECTRONIC COUPLING; HETEROBINUCLEAR ISOMERS; METAL-METAL ELECTRONIC COMMUNICATION;

CHROMIUM COMPOUNDS;

EID: 25444518276     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om050307c     Document Type: Article

References (36)

1. Ceccon, A.; Santi, S.; Orian, L.; Bisello, A. Coord. Chem. Rev. 2004, 248, 683.
2. (a) Delville, M.-H. Inorg. Chim. Acta 1999, 291, 1.
3. (b) de-Azevedo, C. G.; Vollhardt, K. P. C. Synlett 2002, 1019.
4. (c) Santi, S.; Benetollo, F.; Ceccon, A.; Crociani, L.; Gambaro, A.; Ganis, P.; Tiso, M.; Venzo, A. Organometallics 2002, 21, 565.
5. (d) Degrand, C.; Radecki-Sudre, A J. Organomet, Chem. 1984, 268, 63.
6. (e) Yeung, L. K.; Kim, J. E.; Chung, D. Y. K.; Rieger, P. H.; Sweigart, A. Organometallics 1996, 15, 3891.
7. (f) Bonifaci, C.; Carta, G.; Ceccon, A.; Gambaro, A.; Santi, S.; Venzo, A. Organometallics 1996, 15, 1630
8. (g) Burgos, F.; Chavez, I.; Manriquez, J. M.; Valderrama, M.; Lago, E.; Molins, E.; Delpech, F.; Castel, A.; Riviere, P. Organometallics 2001, 20, 1287.
9. (a) Barlow, S.; O'Hare, D. Chem. Rev. 1997, 97, 637.
10. (b) Ward, M. D. Acc. Chem. Res. 1998, 31, 842.
11. (c) Paul, F.; Lapinte, C. Coord. Chem. Rev. 1998, 178-180, 431.
12. (d) Belser, P.; Bernhard, S.; Blum, C.; Beyeler, A.; De Cola, L.; Balzani, V. Coord. Chem. Rev. 1999, 190-192, 155.
13. (e) Heck, J.; Dabek, S.; Meyer-Fredrichsen, T.; Wong, H. Coord. Chem. Rev. 1999, 190-192, 1217.
14. (f) Benniston, C. A.; Harriman, A.; Li, P.; Sams, C. A.; Ward, M. D. J. Am. Chem. Soc. 2004, 125, 13630.
15. (g) Roué, S.; Lapinte, C.; Bataille. T. Organometallics 2004, 23, 2558.
16. (a) Manriquez, J. M.; Ward, M. D.; Reiff, W. M.; Calabrese, J. C.; Jones, N. L.; Carroll, P. J.; Bunel, E. E.; Miller, J. S. J. Am. Chem. Soc. 1995, 117, 6182.
17. (b) Liu, T.-Y, Chen, J. Y.; Tai, C.-C.; Kwan, K. S. Inorg. Chem, 1999, 38, 674.
18. (c) Santi, S.; Ceccon, A.; Carli, F.; Crociani, L.; Bisello, A.; Tiso, M.; Venzo, A. Organometallics 2002, 21, 2679.
19. (d) Scott, W. E.; Craig, D. C.; Colbran, S. B. J. Chem. Soc., Dalton Trans. 2002, 2423.
20. (e) Cotton, F. A.; Liu, C. Y.; Murillo, C. A.; Villagràn D.; Wang, X. J. Am. Chem. Soc. 2004, 125, 14822.
21. (f) D'Alessandro, D. M.; Keene, F. R.; Bergman, S. D.; Kol, M. Dalton Trans. 2005, 332.
22. (a) Plenio, H. Organometallics 1992, 11, 1856.
23. (b) Lee, S. G.; Lee, S. S.; Chung, Y. K. Inorg. Chim. Acta 1999, 256, 215.
24. -1, 2499 reflections measured on a Philips PW1100 instrument. Refinement of 2367 reflections with I ≥ 2σI converged at final R1 = 0.0350 and wR2 = 0.0906.
25. Rogers, R. D.; Atwood, J. L.; Albright, J. L.; Lee. W. A.; Rausch, M. D. Organometallics 1964, 3, 263.
26. Stainer, T.; Tamm, M.; Lutz, B.; van der Maas, J. J. J. Chem. Soc., Chem, Commun. 1996, 1127.
27. (a) te Velde, G.; Bickelhaupt, F. M.; van Gisbergen, S. J. A.; Fonseca Guerra, C.; Baerends, E. J.; Snijders. J. G.; Ziegler, T. Chemistry with ADF. J. Comput. Chem. 2001, 22, 981.
28. (b) Fonseca Guerra, C.; Snijders, J. G.; te Velde, G.; Baerends, E. J. Theor. Chem. Acc. 1998, 99, 391.
29. (c) ADF 2006.01, SCM, Theoretical Chemistry, Vrije Universiteit, Amsterdam: The Netherlands, http://www.scm.com.
30. (a) Creutz, C. Prog. Inorg. Chem. 1983, 30, 1.
31. (b) Chen, P.; Meyer, T. J. Chem. Rev. 1998, 98, 1439.
32. (c) Paul, F Lapinte, C. Coord. Chem. Rev. 1998, 178, 431.
33. 0 is the energy difference between the initial and the final states evaluated from the oxidation potentials (Table 2).
34. (a) Hush, N. S. Prog. Inorg. Chem. 1967, 8, 391.
35. (b) Hush, N. S. Electrochim. Acta 1968, 13,1005.
36. Hush, N. S. Coord. Chem. Rev. 1985, 64, 135.