Extraordinary isotopic fractionation in ozone photolysis

Geophysical Research Letters

Volumn 32, Issue 14, 2005, Pages 1-4

  Miller, Charles E ^a   Onorato, Robert M ^b   Liang, Mao Chang ^c   Yung, Yuk L ^c  

^a CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

^c CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ATMOSPHERIC CHEMISTRY; FRACTIONATION; MATHEMATICAL MODELS; PHOTOLYSIS; ULTRAVIOLET RADIATION; UPPER ATMOSPHERE;

ISOTOPIC FRACTIONATION; OZONE PHOTOLYSIS; ULTRAVIOLET PHOTOLYSIS;

OZONE LAYER;

ISOTOPIC FRACTIONATION; OZONE; PHOTOLYSIS;

EID: 25444487036     PISSN: 00948276     EISSN: None     Source Type: Journal    
DOI: 10.1029/2005GL023160     Document Type: Article

References (23)

1. Anderson, S. M., and J. A. Kaye (1987), Heavy ozone in the stratosphere Comment, Geophys. Res. Lett., 14, 91-93.
2. Anderson, S. M., and K. Mauersberger (1995), Ozone absorption-spectroscopy in search of low-lying electronic states, J. Geophys.Res., 100, 3033-3048.
3. Chakraborty, S., and S. K. Bhattacharya (2003), Oxygen isotopic fractionation during UV and visible light photodissociation of ozone, J. Chem. Phys., 118, 2164-2172.
4. Chapman, S. (1930), A theory of upper atmosphere ozone, Mem. R. Meteorol. Soc., 3, 103-125.
5. Cicerone, R. J., and J. L. McCrumb (1980), Photo-dissociation of isotopically heavy O-2 as a source of atmosphere, Geophys. Res. Lett., 7, 251-254.
6. Flaud, J. M., and R. Bacis (1998), The ozone molecule: Infrared and microwave spectroscopy, Spectrochim. Acta, Part A, 54, 3-16.
7. Gao, Y. Q., and R. A. Marcus (2001), Strange and unconventional isotope effects in ozone formation, Science, 293, 259-263.
8. Gellene, G. I. (1996), An explanation for symmetry-induced isotopic fractionation in ozone, Science, 274, 1344-1346.
9. Gladstone, G. R., M. Allen, and Y. L. Yung (1996), Hydrocarbon photochemistry in the upper atmosphere of Jupiter, Icarus, 119, 1-52.
10. Heidenreich, J. E., and M. H. Thiemens (1983), A non-mass-dependent isotope effect in the production of ozone from molecular-oxygen, J. Chem. Phys., 78, 892-895.
11. Houston, P. L., A. G. Suits, and R. Toumi (1996), Isotopic enrichment of heavy ozone in the stratosphere, J. Geophys. Res., 101, 18,829-18,834.
12. Irion, F. W., M. R. Gunson, C. P. Rinsland, Y. L. Yung, M. C. Abrams, A. Y. Chang, and A, Goldman (1996), Heavy ozone enrichments from ATMOS infrared solar spectra, Geophys. Res. Lett., 23, 2377-2380.
13. Johnson, D. G., K. W. Jucks, W. A. Traub, and K. V. Chance (2000), Isotopic composition of stratospheric ozone, J. Geophys. Res.,105, 9025-9031.
14. Kaye, J. A. (1986), Theoretical-analysis of isotope effects on ozone formation in oxygen photochemistry, J. Geophys. Res., 91, 7865-7874.
15. Kaye, J. A., and D. F. Strobel (1983), Enhancement of heavy ozone in the Earth's atmosphere, J. Geophys. Res., 88, 8447-8452.
16. Liang, M., G. A. Blake, and Y. L. Yung (2004), A semianalytic model for photo-induced isotopic fractionation in simple molecules, J. Geophys. Res., 109, D10308, doi:10.1029/2004JD004539.
17. Mauersberger, K., B. Erbacher, D. Krankowsky, J. Gunther, and R. Nickel (1999), Ozone isotope enrichment: Isotopomer-specific rate coefficients, Science, 283, 370-372.
18. Mauersberger, K., D. Krankowsky, and C. Janssen (2003), Oxygen isotope processes and transfer reactions, Space Sci. Rev., 106, 265-279.
19. Meier, A., and J. Notholt (1996), Determination of the isotopic abundances of heavy O-3 as observed in arctic ground-based FTIR-spectra, Geophys. Res. Lett., 23, 551-554.
20. Miller, C. E., and Y. L. Yung (2000), Photo-induced isotopic fractionation, J. Geophys. Res., 105, 29,039-29,051.
21. Parisse, C., J. Brion, and J. Malicet (1996), UV absorption spectrum of ozone: Structure analysis and study of the isotope effect in the Hartley system, Chem. Phys. Lett., 248, 31-36.
22. Thiemens, M. H. (1999), Atmosphere science-Mass-independent isotope effects in planetary atmospheres and the early solar system, Science, 283, 341-345.
23. Yung, Y. L., and C. E. Miller (1997), Isotopic fractionation of stratospheric nitrous oxide, Science, 278, 1778-1780.