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1842276337
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note
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+) electronic transition thought to be responsible for the continuum absorption, the shifts are similar to those reported in Table 1.
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26
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1842385036
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note
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2O, respectively. Using the same formula to fit our model results, we obtain the corresponding enrichment factors of -15.4 and -13.2, in agreement with experimental values.
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28
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0016322177
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2O would have a large impact on the photolysis rate of the molecule.
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84944833370
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2O isotopomers, exchange with O atoms is potentially important, although the activation energy for the exchange reaction is probably very high. Appropriate laboratory experiments should settle this question.
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Cicerone, R.J.1
McCrumb, J.L.2
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35
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1842362997
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note
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We thank K. Boering, H. Craig, W. DeMore, R. Friedl, Y. Jiang, J. Kaye, T. Rahn, S. Sander, M. Thiemens, and M. Wahlen for valuable discussions and inputs. C.E.M. thanks the National Research Council for a NASA Jet Propulsion Laboratory Research Associateship. This research was supported in part by NASA grant NAG1-1806 to the California Institute of Technology.
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