How polar are ionic liquids? Determination of the static dielectric constant of an imidazolium-based ionic liquid by microwave dielectric spectroscopy

Journal of Physical Chemistry B

Volumn 109, Issue 36, 2005, Pages 17028-17030

  Wakai, Chihiro ^a,b   Oleinikova, Alla ^a   Ott, Magnus ^a   Weingärtner, Hermann ^a  

^a RUHR UNIVERSITY BOCHUM   (Germany)

^b KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

DIELECTRIC MATERIALS; NEGATIVE IONS; PERMITTIVITY; POSITIVE IONS; SALTS;

1-ALKYL-3-METHYLIMIDAZOLIUM SALTS; DIELECTRIC FUNCTION; DIELECTRIC SPECTROSCOPY; IONIC LIQUIDS;

ORGANIC SOLVENTS;

EID: 25444467784     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp053946+     Document Type: Article

References (32)

1. (a) Seddon, K. R. J. Chem. Technol. Biotech. 1997, 68, 351.
2. (b) Wasserscheid P.; Keim W. Angew. Chem., Int. Ed. 2000, 39, 3772.
3. (c) Welton, T. Chem. Rev. 1999, 99, 2071.
4. (d) Ionic Liquids in Synthesis; Wasserscheid, P., Welton, T., Eds.; Wiley-VCH: Weinheim, 2003.
5. (a) Reichardt, C. Green Chem. 2005, 7, 339.
6. (b) Wasserscheid, P.; Gordon, C. M.; Hilgers, C.; Muldoon, M. J.; Dunkin, I. R. Chem. Commun. 2001, 1186.
7. (c) Aki, S. N. V. K.; Brennecke, J. F.; Samanta, A. Chem. Commun. 2001, 413.
8. (d) Carmichael, A. J.; Seddon, K. R. J. Phys. Org. Chem. 2000, 13, 591.
9. (e) Crowhurst, L.; Mawdseley, P. R.; Perez-Arlandiz, J. M.; Salter, P. A. Welton, T. Phys. Chem. Chem. Phys. 2003, 5, 2790.
10. (f) Bonhôte, P.; Dias, A.-P.; Papageorgiu, N. Kalyanasundaram, K.; Grätzel, G. Inorg. Chem. 1996, 35, 1168.
11. Huddleston, J. G.; Willauer, H. D.; Swatloski, R. P.; Visser, A. E.; Rodgers, R. D. Chem. Commun. 1998, 1765.
12. Anderson, J. L.; Ding, J.; Welton, T.; Armstrong, D. W. J. Am. Chem. Soc. 2002, 124, 14247.
13. Earle, M. J.; Engel, B. S.; Seddon, K. R. Austr. J. Chem. 2004, 57, 149.
14. (a) Kaatze U. J. Solution Chem. 1997, 26, 1049.
15. (b) Buchner, R.; Hölzl, C.; Stauber, J.; Barthel, J. Phys. Chem. Chem. Phys. 2002, 4, 2169.
16. (c) Buchner, R. In Novel Approaches for the Structure and Dynmics of Liquids; Samios, J., Durov, V. A., Eds.; NATO Sciences Series II. Vol. 133, Kluwer: Dordrecht, 2004; p 265-288.
17. Angell, C. A. Chem. Rev. 1990, 90, 523.
18. Weingärtner, H.; Knocks, A.; Schrader, W.; Kaatze, U. J. Phys. Chem. A 2001, 105, 8646.
19. Wakai, C.; Oleinikova, A.; Weingärtner, H., to be published.
20. Oleinikova, A.; Sasisanker, P.; Weingärtner, H. J. Phys. Chem. B 2004, 108, 8467.
21. (a) Böttcher, C. J. F. Theory of Dielectric Polarisation, Elsevier: Amsterdam, 1972: Vol. 1.
22. (b) Böttcher, C. J. F.; Bordewijk, P. Theory of Dielectric Polarisation, Elsevier: Amsterdam, 1978; Vol. 2.
23. Asaki, M. L. T.; Redondo, A.; Zawodzinski, T. A.; Taylor, A. J. J. Chem. Phys. 2002, 116, 7579.
24. Buchner, R. Hefter, G. T.; May P. M. J. Phys. Chem. A 1999, 103, 1.
25. See. e.g., (a) Morrow T. I.; Maginn, E. J. J. Phys. Chem. B 2002, 106, 12807.
26. (b) Urahata S. M.; Ribeiro, M. C. C. J. Chem. Phys. 2005, 122, 024511.
27. (a) Ingram, J. A.; Moog, R. S.; Ito, N.; Biswas R.; Maroncelli, M. J. Phys. Chem. B 2003, 107, 5296.
28. (b) Ito, N.; Arzhantsev, S.; Heitz, M. Maroncelli, M. J. Phys. Chem. B 2004, 108, 5771.
29. (c) Chowdhury, P. K. Halder, M.; Sanders, L.; Calhoun, T.; Anderson, J. L.; Armstrong, D. W. Song, X.; Petrich, J. W. J. Phys. Chem. B 2004, 108, 10245.
30. Antony, J. H.; Dölle, A.; Merten, D.; Wasserscheid, P.; Carper, W. R.; Wahlbeck, P. G. J. Phys. Chem. B 2005, 109, 6676.
31. Cole, R. H.; Davidson, D. W. J. Chem. Phys. 1950, 18, 1417.
32. Znamenski, V.; Kobrak, M. J. Phys. Chem. B 2004, 108, 1072.