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note
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This was confirmed for the homo-PIC synthesized by our method although the second endothermic DSC peak near 127°C is unlikely to be the isotropic transition temperature as claimed in ref 27. Polarized optical microscopy showed the isotropization temperature is well above 150°C where its structural identification is complicated by the accompanying cross-linking reaction.
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29
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2542629401
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note
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In PIC(23K)/PS(39K) which has a rod fraction of 37%, we observed the glass transition of PS block near 77°C, two endothermic peaks at 102 and 128°C and a broad exothermic curve for cross-linking reaction above the second melting through 200°C.
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30
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2542524299
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note
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The films were cast from solution in THF with concentrations of 5-15%.
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31
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0038103756
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w of 23 000 g/mol.
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34
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