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Volumn 44, Issue 36, 2005, Pages 5891-5894

Reversible hydride generation and release from the ligand of [Ru(pbn)(bpy)2](PF6)2 driven by a pbn-localized redox reaction

Author keywords

Hydrogen transfer; N ligands; Redox chemistry; Reduction; Ruthenium

Indexed keywords

CATALYSIS; CHARGED PARTICLES; ELECTROCHEMISTRY; HYDRIDES; HYDROGEN; REDOX REACTIONS; REDUCTION;

EID: 24944576124     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200500760     Document Type: Article
Times cited : (54)

References (33)
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    • 24944505055 scopus 로고    scopus 로고
    • [11] All structures were solved by direct methods and expanded using Fourier techniques. Refinements were performed anisotropically for all non-hydrogen atoms by the full-matrix least-squares method. Hydrogen atoms were placed at the calculated positions and were included in the structure calculation without further refinement of the parameters. CCDC-248968 (1) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
  • 32
    • 24944437446 scopus 로고    scopus 로고
    • note
    • We tried to isolate and recrystallize complex 2. However, good single crystals of 2 were not obtained, since recrystallization of 2 gave a mixture of 1 and 2. Complex 2 is unstable in air and in solution under inert atmosphere, and slowly changed into complex 1. ESI-MS analysis showed 2 at first, but the parent signal of 1 gradually appeared with time. Since the recrystallization has not resulted in purification of 2, the elemental analysis was not completely satisfactory.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.