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Volumn 23, Issue 9, 2004, Pages 2027-2047

Renewable monomer feedstocks via olefin metathesis: Fundamental mechanistic studies of methyl oleate ethenolysis with the first-generation grubbs catalyst

Author keywords

[No Author keywords available]

Indexed keywords

GRUBBS CATALYSTS; MOLECULAR MODELING; MONOMER FEEDSTOCKS; OLEFIN METATHESIS;

EID: 2442625578     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0341799     Document Type: Article
Times cited : (180)

References (55)
  • 37
    • 2442519588 scopus 로고    scopus 로고
    • Grubbs, R. H.; Nguyen, S. T.; Johnson, L. K.; Hillmyer, M. S.; Fu, G. C. WO 9604289, 1996
    • Grubbs, R. H.; Nguyen, S. T.; Johnson, L. K.; Hillmyer, M. S.; Fu, G. C. WO 9604289, 1996.
  • 41
    • 2442583800 scopus 로고    scopus 로고
    • See the Supporting Information
    • See the Supporting Information.
  • 42
    • 0003471204 scopus 로고    scopus 로고
    • Sohrodinger, Inc., Portland, OR
    • Jaguar 4.0; Sohrodinger, Inc., Portland, OR, 2000.
    • (2000) Jaguar 4.0
  • 43
    • 2442556424 scopus 로고    scopus 로고
    • note
    • 48 During a typical batch experiment only low levels of trans olefin are observed, and therefore, this impact of catalyst activity should be minimal, This effect will need to be considered in future process studies, though, as trans olefin will build up on recycling of the metathesis mixture and thus could impact catalyst performance to a greater degree.
  • 47
    • 2442590032 scopus 로고    scopus 로고
    • note
    • This assumption has been tested by comparing the rate of terminal olefin coupling with either 1-decene or methyl 9-decenoate, as shown in Figure 26 in the Appendix. The near-identical conversion rates for these two substrates support the postulate of equal reactivity for 4 and 5.
  • 53
    • 2442545786 scopus 로고    scopus 로고
    • note
    • 51
  • 54
    • 2442560685 scopus 로고    scopus 로고
    • note
    • 51


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.