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This assignment is, at the moment, based solely on the low-field value of the chemical shift compared with simple Pd(II) adducts, consistent with literature data for related five-membered palladacycles formed on orthometallation of triarylphosphites. See, for example: R.B. Bedford, S.L. Hazelwood, M.E. Limmert, D.A. Albisson, S.M. Draper, P.N. Scully, S.J. Coles, and M.B. Hursthouse Chem. Eur. J. 2003 3126
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0035959464
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2PCl with (2S,2′S)-1,1′-(ethane-1,2-diyl)bis(pyrrolidine-2,1-diyl)dimethanol in toluene with triethylamine as base. The chiral diol was prepared according to a literature method: Q. Xu, H. Wang, X. Pan, A.S.C. Chan, and T.-K. Yang Tetrahedron Lett. 2001 6171
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Manuscript in preparation.
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Bedford, R. B.; Betham, M; Blake, M. E.; Coles, S. J.; Hursthouse, M. B.; Pilarski, L. T.; Pringle, P. G.; Wingad, R. Manuscript in preparation.
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Bedford, R.B.1
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Hursthouse, M.B.5
Pilarski, L.T.6
Pringle, P.G.7
Wingad, R.8
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