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Volumn 18, Issue 17, 1999, Pages 3511-3518

Resolution of Benzylcyclohexylphenylphosphine by Palladium(II)-Amine Metallacycles. A New Ligand for Asymmetric Hydrovinylation

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EID: 0000893822     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om990302d     Document Type: Article
Times cited : (77)

References (63)
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    • It should be noted that reaction times longer than 30 min (at 15°C) afford a yield near 100% (calculated as conversion of starting olefin), but a significant decrease in the selectivity is also observed (see entry 6)
    • It should be noted that reaction times longer than 30 min (at 15°C) afford a yield near 100% (calculated as conversion of starting olefin), but a significant decrease in the selectivity is also observed (see entry 6).
  • 58
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    • Small amounts of 2-vinylnaphthalene dimers were observed, but not significantly bigger than those contained in the recrystallized product used as starting material
    • Small amounts of 2-vinylnaphthalene dimers were observed, but not significantly bigger than those contained in the recrystallized product used as starting material.


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