Enantioselective total synthesis and determination of the absolute configuration of the 4,6,8,10,16,18-hexamethyldocosane from Antitrogus parvulus

Angewandte Chemie - International Edition

Volumn 44, Issue 33, 2005, Pages 5267-5269

  Herber, Christian ^a   Breit, Bernhard ^a  

^a UNIVERSITY OF FREIBURG   (Germany)

Author keywords

Asymmetric synthesis; C C coupling; Grignard reaction; Organocopper reagents; Total synthesis

Indexed keywords

ALLYL RESINS; CATALYSIS; COPPER; REACTION KINETICS; SUBSTITUTION REACTIONS;

ASYMMETRIC SYNTHESIS; C-C COUPLING; GRIGNARD REACTIONS; ORGANOCOPPER REAGENTS; TOTAL SYNTHESIS;

SYNTHESIS (CHEMICAL);

4,6,8,10,16,18 HEXAMETHYLDOCOSANE; 4,6,8,10,16,18-HEXAMETHYLDOCOSANE; ALKANE;

ANIMAL; ARTICLE; BEETLE; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION; STEREOISOMERISM; SYNTHESIS;

ALKANES; ANIMALS; BEETLES; MOLECULAR CONFORMATION; MOLECULAR STRUCTURE; STEREOISOMERISM;

EID: 24044520054     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200501612     Document Type: Article

References (15)

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15. A comparison of the analytical data of the natural material and synthetic compounds 1a and 1b can be found in the Supporting Information.