Synthesis, X-ray crystallographic, and dynamic 1H NMR studies of crown-tetrathia[3.3.3.3]metacyclophanes - Conformational control by cooperative intramolecular C-H⋯π interaction both in solid state and in solution

Tetrahedron

Volumn 61, Issue 39, 2005, Pages 9248-9256

  Xu, Jian Wei ^a,b   Wang, Wei Ling ^a   Lai, Yee Hing ^a  

^a NATIONAL UNIVERSITY OF SINGAPORE   (Singapore)

^b INSTITUTE OF MATERIALS RESEARCH AND ENGINEERING   (Singapore)

Author keywords

C H Interaction; Conformation; Cyclophane; Synthesis

Indexed keywords

3,11,19,27 TETRATHIA 7,15,23,31 BISCROWN 4(6),8,14,16,22,24,30,32,33,34,35, 36 DODECAMETHYL[3.3.3.3]METACYCLOPHANE; 3,11,19,27 TETRATHIA 7,15,23,31 BISCROWN 5(6),8,14,16,22,24,30,32,33,34,35, 36 DODECAMETHYL[3.3.3.3]METACYCLOPHANE; 3,11,19,27 TETRATHIA 7,15,23,31 BISCROWN 6(6),8,14,16,22,24,30,32,33,34,35, 36 DODECAMETHYL[3.3.3.3]METACYCLOPHANE; BENZENE; HYDROGEN; METACYCLOPHANE DERIVATIVE; METHYL GROUP; PROTON; UNCLASSIFIED DRUG;

ARTICLE; CALCULATION; CHEMICAL STRUCTURE; CONFORMATION; DYNAMIC EXERCISE; ENTHALPY; LOW TEMPERATURE; MOLECULAR INTERACTION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PRIORITY JOURNAL; PROTON NUCLEAR MAGNETIC RESONANCE; QUANTITATIVE ANALYSIS; ROOM TEMPERATURE; SOLID STATE; SYNTHESIS; X RAY ANALYSIS; X RAY CRYSTALLOGRAPHY;

THIA;

EID: 23944435630     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tet.2005.07.071     Document Type: Article

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