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Volumn 24, Issue 16, 2005, Pages 3974-3981

Higher valent metal pentadienyl chemistry: Syntheses, structures, and reactions of Zr(6,6-dmch) 2X 2 complexes (dmch = dimethylcyclohexadienyl; X = Cl, Br, I) and related species

Author keywords

[No Author keywords available]

Indexed keywords

CARBON ATOMS; FACILE REACTIONS; LIGANDS; OXIDATIVE ADDITIONS;

EID: 23844544728     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om058017j     Document Type: Article
Times cited : (17)

References (50)
  • 18
    • 33645360428 scopus 로고    scopus 로고
    • Basta, R.; Arif, A. M.; Ernst, R. D. Unpublished results
    • (a) Basta, R.; Arif, A. M.; Ernst, R. D. Unpublished results.
  • 19
    • 33645368219 scopus 로고    scopus 로고
    • Ph.D. Thesis, University of Utah
    • (b) Basta, R. Ph.D. Thesis, University of Utah, 2004.
    • (2004)
    • Basta, R.1
  • 41
    • 33645335634 scopus 로고    scopus 로고
    • note
    • Notably, while the first π-donor interaction would be expected to enhance the metal-pentadienyl bonding by making the metal center more electron rich, the second interaction would necessarily compete with the metal-dienyl bonding to avoid a 20-electron configuration.
  • 47
    • 33645347610 scopus 로고    scopus 로고
    • note
    • The observed distances were approximated as averages of the actual (presumably, "corrected") distances, weighted linearly with the relative electron densities expected for the 91:9 atomic ratios.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.