The first asymmetric epoxidation using a combination of achiral (salen)manganese(III) complex and chiral amine

Tetrahedron

Volumn 53, Issue 28, 1997, Pages 9541-9552

  Hashihayata, Takashi ^a   Ito, Yoshio ^a   Katsuki, Tsutomu ^a  

^a KYUSHU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CHROMENE DERIVATIVE; LIGAND; MANGANESE DERIVATIVE; SOLVENT; SPARTEINE; SULFOXIDE;

ARTICLE; CATALYST; CHIRALITY; COMPLEX FORMATION; ENANTIOMER; EPOXIDATION; OPTICAL ROTATION; PRIORITY JOURNAL; SYNTHESIS;

EID: 0030874375     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(97)00633-9     Document Type: Article

References (28)

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15. Compound 12 was prepared from (-)-menthone as described below. (formula presented)
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27. HPLC data of 20, 25 and 26 are as follows. 20: DAICEL CHIRALCEL OB-H, hexane/2-propanol 9/1, flow rate: 0.5 ml/min, retention time: 13 min for (3S,4S)-isomer and 22 min for (3R,4R)-isomer. 25: DAICEL CHIRALCEL OB-H, hexane/2-propanol 9/1, flow rate: 0.5 ml/min, retention time: 15 min for (15,2R)-isomer and 18 min for (1R,2S)-isomer. 26: DAICEL CHIRALCEL OJ, hexane/2-propanol 4/1, flow rate: 0.5 ml/min, retention time: 19 min for (15,2R)-isomer and 23 min for (1R,2S)-isomer.
28. HPLC data of 27 are as follows. DAICEL CHIRALCEL OD, hexane/2-propanol 400/1, now rate: 0.4 ml/min, retention time: 23 min for (S)-isomer and 26 min for (R)-isomer).