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Volumn 119, Issue 40, 1997, Pages 9550-9557

Synthesis, characterization, optical spectroscopic, electronic structure, and second-order nonlinear optical (NLO) properties of a novel class of donor-acceptor bis(salicylaldiminato)nickel(II) Schiff base NLO chromophores

Author keywords

[No Author keywords available]

Indexed keywords

LIGAND; METAL COMPLEX; ORGANOMETALLIC COMPOUND; SCHIFF BASE;

EID: 0030732057     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja971349y     Document Type: Article
Times cited : (305)

References (64)
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    • For recent reviews on NLO materials see, for example: (a) Ledoux, I.; Zyss, J. In Novel Optical Materials and Applications; Khoo, I. C., Simoni, F., Umeton, C., Eds; John Wiley & Sons: New York, 1997.
    • (1997) Novel Optical Materials and Applications
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  • 17
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    • (a) For a recent review of NLO studies involving organometallic and coordination complexes, see: Long, N. J. Angew. Chem., Int. Ed. Engl. 1995. 34, 21.
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  • 19
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    • (1997) Chem. Mater. , vol.9 , pp. 440
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    • note
    • 9c within a perturbation series expansion.
  • 39
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  • 40
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    • note
    • Although a mixture of three stereoisomer s could in principle be formed in the condensation reaction to obtain ligands 4-6, the stereoisomer having both trans-imine linkages, i.e., with the enolimine tautomeric structure I in Scheme 1, is expected to be predominant. Moreover, since complexation involves only the dianion of stereoisomer I, no attempts to separate the mixture of the three stereoisomers were made.
  • 48
    • 9844257432 scopus 로고    scopus 로고
    • note
    • jjj)
  • 52
    • 9844221823 scopus 로고    scopus 로고
    • note
    • i components.
  • 53
    • 9844253745 scopus 로고    scopus 로고
    • note
    • ge and βμ values are computed because the ground- and excited-state dipole moments are both directed between the oxygen donor atoms.
  • 54
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    • note
    • 27b
  • 64
    • 9844235197 scopus 로고    scopus 로고
    • note
    • 6a on 6a, an anti conformation was adopted, thus resulting in a slightly different calculated NLO response.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.