Stabilization of vinylidene-type and acetylene-type Si2H 2 species by coordination with rhodium(I) and platinum(O) complexes. Theoretical proposals

Organometallics

Volumn 24, Issue 15, 2005, Pages 3655-3663

  Kuramoto, Yuki ^a   Sawai, Noriyuki ^a   Fujiwara, Yusuke ^a   Sumimoto, Michinori ^a   Nakao, Yoshihide ^a   Sato, Hirofumi ^a   Sakaki, Shigeyoshi ^a,b  

^a KYOTO UNIVERSITY   (Japan)

^b KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; COMPLEXATION; ISOMERIZATION; PLATINUM; RHODIUM; SYNTHESIS (CHEMICAL);

ACTIVATION BARRIERS; PLATINUM(0) COMPLEXES; RH COMPLEX; SI2H2 SPECIES;

SILICON COMPOUNDS;

EID: 22944448330     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om050337f     Document Type: Article

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56. 2, which is taken in 1-Pt.
57. xy orbital mainly participates in the π-back-donation.
58. 41b
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61. 2).
62. 2 isomers presented here are similar to those reported in the previous work.