Tetrakis(2,4,6-triisopropylphenyl)diplumbene: A molecule with a lead- lead double bond

Angewandte Chemie - International Edition

Volumn 38, Issue 1-2, 1999, Pages 187-189

  Stürmann, Martin ^a   Saak, Wolfgang ^a   Marsmann, Heinrich ^b   Weidenbruch, Manfred ^a  

^a UNIVERSITY OF OLDENBURG   (Germany)

^b Fb Chemie der Universitat   (Germany)

Author keywords

Carbene analogues; Elements; Lead; Main group; Multiple bonds

Indexed keywords

LEAD;

ARTICLE; CHEMICAL BOND; DIMERIZATION; MOLECULAR INTERACTION; STRUCTURE ANALYSIS;

EID: 0039808675     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (34)

1. Reviews of disilenes: R. West, Angew. Chem. 1987, 99, 1231; Angew. Chem. Int. Ed. Engl. 1987, 26, 1202; G. Raabe, J. Michl in The Chemistry of Organic Silicon Compounds, Part 2 (Eds.: S. Patai, Z. Rappoport), Wiley, Chichester, 1089, p. 1015; T. Tsumuraya, S. A. Batcheller, S. Masamune, Angew. Chem. 1991, 103, 916; Angew. Chem. Int. Ed. Engl. 1991, 30, 902; M. Weidenbruch, Coord. Chem. Rev. 1994, 130, 275; R. Okazaki, R. West in Multiply Bonded Main Group Metals and Metalloids (Eds.: R. West, F. G. A. Stone), Academic Press, San Diego, 1996, p. 232.
2. Reviews of disilenes: R. West, Angew. Chem. 1987, 99, 1231; Angew. Chem. Int. Ed. Engl. 1987, 26, 1202; G. Raabe, J. Michl in The Chemistry of Organic Silicon Compounds, Part 2 (Eds.: S. Patai, Z. Rappoport), Wiley, Chichester, 1089, p. 1015; T. Tsumuraya, S. A. Batcheller, S. Masamune, Angew. Chem. 1991, 103, 916; Angew. Chem. Int. Ed. Engl. 1991, 30, 902; M. Weidenbruch, Coord. Chem. Rev. 1994, 130, 275; R. Okazaki, R. West in Multiply Bonded Main Group Metals and Metalloids (Eds.: R. West, F. G. A. Stone), Academic Press, San Diego, 1996, p. 232.
3. Reviews of disilenes: R. West, Angew. Chem. 1987, 99, 1231; Angew. Chem. Int. Ed. Engl. 1987, 26, 1202; G. Raabe, J. Michl in The Chemistry of Organic Silicon Compounds, Part 2 (Eds.: S. Patai, Z. Rappoport), Wiley, Chichester, 1089, p. 1015; T. Tsumuraya, S. A. Batcheller, S. Masamune, Angew. Chem. 1991, 103, 916; Angew. Chem. Int. Ed. Engl. 1991, 30, 902; M. Weidenbruch, Coord. Chem. Rev. 1994, 130, 275; R. Okazaki, R. West in Multiply Bonded Main Group Metals and Metalloids (Eds.: R. West, F. G. A. Stone), Academic Press, San Diego, 1996, p. 232.
4. Reviews of disilenes: R. West, Angew. Chem. 1987, 99, 1231; Angew. Chem. Int. Ed. Engl. 1987, 26, 1202; G. Raabe, J. Michl in The Chemistry of Organic Silicon Compounds, Part 2 (Eds.: S. Patai, Z. Rappoport), Wiley, Chichester, 1089, p. 1015; T. Tsumuraya, S. A. Batcheller, S. Masamune, Angew. Chem. 1991, 103, 916; Angew. Chem. Int. Ed. Engl. 1991, 30, 902; M. Weidenbruch, Coord. Chem. Rev. 1994, 130, 275; R. Okazaki, R. West in Multiply Bonded Main Group Metals and Metalloids (Eds.: R. West, F. G. A. Stone), Academic Press, San Diego, 1996, p. 232.
5. Reviews of disilenes: R. West, Angew. Chem. 1987, 99, 1231; Angew. Chem. Int. Ed. Engl. 1987, 26, 1202; G. Raabe, J. Michl in The Chemistry of Organic Silicon Compounds, Part 2 (Eds.: S. Patai, Z. Rappoport), Wiley, Chichester, 1089, p. 1015; T. Tsumuraya, S. A. Batcheller, S. Masamune, Angew. Chem. 1991, 103, 916; Angew. Chem. Int. Ed. Engl. 1991, 30, 902; M. Weidenbruch, Coord. Chem. Rev. 1994, 130, 275; R. Okazaki, R. West in Multiply Bonded Main Group Metals and Metalloids (Eds.: R. West, F. G. A. Stone), Academic Press, San Diego, 1996, p. 232.
6. Reviews of disilenes: R. West, Angew. Chem. 1987, 99, 1231; Angew. Chem. Int. Ed. Engl. 1987, 26, 1202; G. Raabe, J. Michl in The Chemistry of Organic Silicon Compounds, Part 2 (Eds.: S. Patai, Z. Rappoport), Wiley, Chichester, 1089, p. 1015; T. Tsumuraya, S. A. Batcheller, S. Masamune, Angew. Chem. 1991, 103, 916; Angew. Chem. Int. Ed. Engl. 1991, 30, 902; M. Weidenbruch, Coord. Chem. Rev. 1994, 130, 275; R. Okazaki, R. West in Multiply Bonded Main Group Metals and Metalloids (Eds.: R. West, F. G. A. Stone), Academic Press, San Diego, 1996, p. 232.
7. Reviews of disilenes: R. West, Angew. Chem. 1987, 99, 1231; Angew. Chem. Int. Ed. Engl. 1987, 26, 1202; G. Raabe, J. Michl in The Chemistry of Organic Silicon Compounds, Part 2 (Eds.: S. Patai, Z. Rappoport), Wiley, Chichester, 1089, p. 1015; T. Tsumuraya, S. A. Batcheller, S. Masamune, Angew. Chem. 1991, 103, 916; Angew. Chem. Int. Ed. Engl. 1991, 30, 902; M. Weidenbruch, Coord. Chem. Rev. 1994, 130, 275; R. Okazaki, R. West in Multiply Bonded Main Group Metals and Metalloids (Eds.: R. West, F. G. A. Stone), Academic Press, San Diego, 1996, p. 232.
8. Reviews on digermenes and distannenes: K. M. Baines, W. G. Stibbs in Multiply Bonded Main Group Metals and Metalloids (Eds.: R. West, F. G. A. Stone), Academic Press, San Diego 1996, p. 275: M. Driess, H. Grützmacher, Angew. Chem. 1996, 108, 900; Angew. Chem. Int. Ed. Engl. 1996, 35, 827.
9. Reviews on digermenes and distannenes: K. M. Baines, W. G. Stibbs in Multiply Bonded Main Group Metals and Metalloids (Eds.: R. West, F. G. A. Stone), Academic Press, San Diego 1996, p. 275: M. Driess, H. Grützmacher, Angew. Chem. 1996, 108, 900; Angew. Chem. Int. Ed. Engl. 1996, 35, 827.
10. Reviews on digermenes and distannenes: K. M. Baines, W. G. Stibbs in Multiply Bonded Main Group Metals and Metalloids (Eds.: R. West, F. G. A. Stone), Academic Press, San Diego 1996, p. 275: M. Driess, H. Grützmacher, Angew. Chem. 1996, 108, 900; Angew. Chem. Int. Ed. Engl. 1996, 35, 827.
11. 2: synthesis: P. J. Davidson, M. F. Lappert, J. Chem. Soc. Chem. Commun. 1973, 317: P. J. Davidson, D. H. Harris, M. F. Lappert, J. Chem. Soc. Dalton Trans. 1976, 2268; structure: K. W. Klinkhammer, W. Schwarz, unpublished results. We thank Dr. Klinkhammer for advanced communication.
12. 2: synthesis: P. J. Davidson, M. F. Lappert, J. Chem. Soc. Chem. Commun. 1973, 317: P. J. Davidson, D. H. Harris, M. F. Lappert, J. Chem. Soc. Dalton Trans. 1976, 2268; structure: K. W. Klinkhammer, W. Schwarz, unpublished results. We thank Dr. Klinkhammer for advanced communication.
13. 2: synthesis: P. J. Davidson, M. F. Lappert, J. Chem. Soc. Chem. Commun. 1973, 317: P. J. Davidson, D. H. Harris, M. F. Lappert, J. Chem. Soc. Dalton Trans. 1976, 2268; structure: K. W. Klinkhammer, W. Schwarz, unpublished results. We thank Dr. Klinkhammer for advanced communication.
14. C. Eaborn, T. Ganicz, P. B. Hitchcock, J. D. Smith, S. E. Sözerli, Organometalics 1997, 16, 5621.
15. S. Brooker, J.-K. Buijink, F. T. Edelmann, Organometallics 1991, 10, 25.
16. R. S. Simons, L. Pu, M. M. Olmstead, P. P. Power, Organometallics 1997, 16, 1920.
17. K. W. Klinkhammer, T. F. Fässler, H. Grütmacher, Angew. Chem. 1998, 110, 114; Angew. Chem. Int. Ed. 1998, 37, 124.
18. K. W. Klinkhammer, T. F. Fässler, H. Grütmacher, Angew. Chem. 1998, 110, 114; Angew. Chem. Int. Ed. 1998, 37, 124.
19. M. Stürmann, M. Weidenbruch, K. W. Klinkhammer, F. Lissner, H. Marsmann, Organometallics 1998, 17, 4425.
20. G. Trinquier, J. Am. Chem. Soc. 1990, 112, 2130.
21. H. Jacobsen, T. Ziegler, J. Am. Chem. Soc. 1994, 116, 3667.
22. M. Weidenbruch, S. Willms, W. Saak, G. Henkel, Angew. Chem. 1997, 109, 2612; Angew. Chem. Int. Ed. Engl. 1997, 36, 2503.
23. M. Weidenbruch, S. Willms, W. Saak, G. Henkel, Angew. Chem. 1997, 109, 2612; Angew. Chem. Int. Ed. Engl. 1997, 36, 2503.
24. S. Masamune, L. R. Sita, J. Am. Chem. Soc. 1985, 107, 6390; A. Schäfer, M. Weidenbruch, W. Saak, S. Pohl, H. Marsmann, Angew. Chem. 1991, 103, 873 and 978; Angew. Chem. Int. Ed. Engl. 1991, 30, 834 and 962: M. Weidenhruch, A. Schäfer, H. Kilian, S. Pohl, W. Saak, H. Marsmann, Chem. Ber. 1992, 125, 563.
25. S. Masamune, L. R. Sita, J. Am. Chem. Soc. 1985, 107, 6390; A. Schäfer, M. Weidenbruch, W. Saak, S. Pohl, H. Marsmann, Angew. Chem. 1991, 103, 873 and 978; Angew. Chem. Int. Ed. Engl. 1991, 30, 834 and 962: M. Weidenhruch, A. Schäfer, H. Kilian, S. Pohl, W. Saak, H. Marsmann, Chem. Ber. 1992, 125, 563.
26. S. Masamune, L. R. Sita, J. Am. Chem. Soc. 1985, 107, 6390; A. Schäfer, M. Weidenbruch, W. Saak, S. Pohl, H. Marsmann, Angew. Chem. 1991, 103, 873 and 978; Angew. Chem. Int. Ed. Engl. 1991, 30, 834 and 962: M. Weidenhruch, A. Schäfer, H. Kilian, S. Pohl, W. Saak, H. Marsmann, Chem. Ber. 1992, 125, 563.
27. S. Masamune, L. R. Sita, J. Am. Chem. Soc. 1985, 107, 6390; A. Schäfer, M. Weidenbruch, W. Saak, S. Pohl, H. Marsmann, Angew. Chem. 1991, 103, 873 and 978; Angew. Chem. Int. Ed. Engl. 1991, 30, 834 and 962: M. Weidenhruch, A. Schäfer, H. Kilian, S. Pohl, W. Saak, H. Marsmann, Chem. Ber. 1992, 125, 563.
28. K. Shibata, N. Tokitoh, R. Okazaki, Tetrahedron Lett. 1993, 34, 1495; N. Tokitoh, N. Kano, K. Shibata, R. Okazaki, Organometallics 1995, 14, 3121.
29. K. Shibata, N. Tokitoh, R. Okazaki, Tetrahedron Lett. 1993, 34, 1495; N. Tokitoh, N. Kano, K. Shibata, R. Okazaki, Organometallics 1995, 14, 3121.
30. hH): M. A. DellaBonna, M. C. Cassani, J. M. Keates, G.A. Lawless, M. F. Lappert, M. Stürmann, M. Weidenbruch, J. Chem. Soc. Dalton Trans. 1998, 1187.
31. G,
32. b) Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-102629. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road. Cambridge CB21EZ, UK (fax: (+ 44)1223-336-033: e-mail: deposit @ccdc.cam.ac.uk).
33. G. M. Sheldrick, SHELXL-97, Program for crystal structure refinement, Universität Göttingen, Germany, 1997.
34. P. Pyykkö, Chem. Rev. 1988, 88, 563.