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Volumn , Issue 14, 2005, Pages 3095-3100

Liquid crystals based on hypervalent sulfur fluorides: Exploring the steric effects of ortho-fluorine substituents

Author keywords

Density functional calculations; Fluorination; Hypervalent sulfur fluorides; Liquid crystals; Mesogens; Molecular modelling

Indexed keywords


EID: 22544452743     PISSN: 1434193X     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejoc.200500125     Document Type: Article
Times cited : (63)

References (32)
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    • (Ed.: K. Akiba), Wiley, New York, chapter 10
    • 6-sulfanyl derivatives, see: a) D. Lentz, K. Seppelt in Chemistry of Hypervalent Compounds (Ed.: K. Akiba), Wiley, New York, 1999, chapter 10, p. 295;
    • (1999) Chemistry of Hypervalent Compounds , pp. 295
    • Lentz, D.1    Seppelt, K.2
  • 10
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    • Angew. Chem. Int. Ed. 1999, 38, 1989-1992;
    • (1999) Angew. Chem. Int. Ed. , vol.38 , pp. 1989-1992
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    • 0035901632 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2001, 40, 1480-1484.
    • (2001) Angew. Chem. Int. Ed. , vol.40 , pp. 1480-1484
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    • Angew. Chem. Int. Ed. 2000, 39, 4216-4235;
    • (2000) Angew. Chem. Int. Ed. , vol.39 , pp. 4216-4235
  • 24
    • 79960678031 scopus 로고
    • 2β)S, where Δα is the anisotropy of the polarizability, F the reaction field factor and S the order parameter: a) W. Maier, G. Meier, Z. Naturforsch. 1961, 16A, 262-267;
    • (1961) Z. Naturforsch. , vol.16 A , pp. 262-267
    • Maier, W.1    Meier, G.2
  • 31
    • 22544469026 scopus 로고    scopus 로고
    • note
    • NI = 92.8°C, Δε = 5.3, Δn = 0.0964). The extrapolated values were corrected empirically for differences in the order parameter which are induced by the analyte. For the pure substances, the melting points were identified by differential scanning calorimetry (DSC) and the phases by optical polarization microscopy.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.