Lewis base-catalyzed diastereoselective strecker-type reaction between trimethylsilyl cyanide and chiral sulfinimines

Chemistry Letters

Volumn 34, Issue 4, 2005, Pages 604-605

  Takahashi, Eiki ^a,b   Fujisawa, Hidehiko ^a,b   Yanai, Toshiharu ^a,b   Mukaiyama, Teruaki ^a,b  

^a KITASATO INSTITUTE   (Japan)

^b KITASATO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ACETIC ACID DERIVATIVE; AMMONIUM DERIVATIVE; CYANIDE; IMINE; LEWIS BASE; TRIMETHYLSILYL DERIVATIVE;

ARTICLE; CATALYSIS; CHEMICAL PROCEDURES; CHEMICAL REACTION; CHIRALITY; REACTION ANALYSIS; STRECKER SYNTHESIS;

EID: 21644463713     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2005.604     Document Type: Article

References (32)

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31. NMR data of these compounds [2 (Ss,R), 2 (Ss,S)] were consistent with the data reported in Ref. 1o.
32. 4 (6.0 mg, 0.02 mmol) in THF (0.4 mL) were added successively a solution of TMSCN (23.8 mg, 0.24 mmol) in DMF (0.4 mL) and a solution of fleshly prepared N-sulfinimine 1 (41.9 mg, 0.2 mmol) in DMF (0.4 mL) at -78°C.