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To observe an NMR echo using the usual sequence π/2-τ-π-, the length of the π/2 pulse is reduced if only the central transition is observed. Furthermore, while the length for τ should be exactly twice the π/2 one in the latter case, it can be reduced to half this value when all the transitions are observed, if the dephasing between the nuclear spins is dominated by a quadrupolar origin. In our case, the signal is optimized for the two main lines by the same length of π/2 and a shorter value for π.
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33744599355
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33744563768
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note
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m = 30 ppm) compared to the linewidths (already 130 ppm for NS), and the number of sites with only metallic neighbors could be too small to be detected.
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27
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0012063852
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and references therein
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