Time-resolved EPR studies of main chain radicals from acrylic polymers. Effects of tacticity, solvent, and side group structure on chain stiffness

Journal of Physical Chemistry B

Volumn 109, Issue 21, 2005, Pages 10686-10694

  McCaffrey, Vanessa P ^a   Harbron, Elizabeth J ^a   Forbes, Malcolm D E ^a  

^a University of North Carolina at Chapel Hill   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACRYLIC POLYMERS; HYPERFINE COUPLING CONSTANT; POLYMER CHAIN STIFFNESS; SOLVENT EFFECT;

FREE RADICALS; PARAMAGNETIC RESONANCE; PHOTOLYSIS; REACTION KINETICS; SOLVENTS; STIFFNESS;

ACRYLICS;

EID: 20544450585     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp0501401     Document Type: Article

References (32)

1. Harbron, E. J.; McCaffrey, V. P.; Xu, R.; Forbes, M. D. E. J. Am. Chem. Soc. 2000, 122, 9182.
2. McCaffrey, V. P.; Forbes, M. D. E. Macromolecules 2005, 38, 3334-3341.
3. McCaffrey, V. P.; Harbron, E. J.; Forbes, M. D. E. Macromolecules 2005, 38, 3342-3350.
4. Forbes, M. D. E.; Barborak, J. D.; Dukes, K. E.; Ruberu, S. R. Macromolecules 1994, 27, 1020.
5. Sluggett, G. W.; McGarry, P. F.; Koptyug, I. V.; Turro, N. J. J. Am. Chem. Soc. 1996, 118, 7367-7372.
6. Beck, G.; Lindenan, D.; Schnabel, W. Macromolecules 1977, 10, 135.
7. Liang, R. H.; Tasy, F.-D.; Gupta, A. Macromolecules 1982, 15, 974.
8. Apel, U. M.; Hentschke, R.; Helfrich, J. Macromolecules 1995, 28, 1778.
9. Johnson, J. F.; Porter, R. S. In The Stereochemistry of Macromolecules; Ketley, A. D., Ed.; Marcel Dekker: New York, 1968; Vol. 3, Chapter
10. O'Reilly, J. M.; Teegarden, D. M.; Wignall, G. D. Macromolecules 1985, 18, 2747.
11. Kochi, J. Adv. Free Radical Chem. 1975, 5, 189.
12. Spevacek, J.; Schneider, B. Polymer 1978, 19, 63.
13. Ono, K.; Sasaki, T.; Yamamoto, M.; Yamasaki, Y.; Ute, K.; Hatada, K. Macromolecules 1995, 28, 5012.
14. Grohens, Y.; Prud'homme, R. E.; Schultz, J. Macromolecules 1998, 31, 2545.
15. Fiebig, M.; Kauf, M.; Fair, J.; Endert, H.; Rahe, M.; Basting, D. Appl. Phys. A: Mater. Sci. Process. 1999, 69(Suppl).
16. DeSimone, J. M.; Romack, T.; Betts, D. E.; McClain, J. B. U. S. Patent 5,783,082, 1998.
17. Hoffman, H.; Kalus, J.; Thurn, H. Colloid Polym. Sci. 1983, 261, 1043.
18. Yee, G. G.; Fulton, J. L.; Smith, R. D. J. Phys. Chem. 1992, 96, 6172.
19. Spyros, A.; Dais, P.; Heatley, F. Macromolecules 1994, 27, 6207.
20. Des Cloizeaux, J. Polymers in Solution: Their Modeling and Structure; Clarendon Press: Oxford, U.K., 1990.
21. Tompa, H. Polymer Solutions; Academic Press: New York, 1956.
22. de Gennes, P. G. Scaling Concepts in Polymer Physics; Cornell University Press: Ithaca, NY, 1979.
23. Flory, P. J. Principles of Polymer Chemistry; Cornell University Press: Ithaca, NY, 1953.
24. Verma, N. C.; Fessenden, R. W. J. Chem. Phys. 1976, 65, 2139.
25. McLauchlan, K. A.; Stevens, D. G. Acc. Chem. Res. 1988, 21, 54.
26. Guillet, J. Polymer Photophysics and Photochemistry: An Introduction to the Study of Photoprocesses in Macromolecules; Cambridge University Press: New York, 1987.
27. Fox, R. B.; Isaacs, L. G.; Stokes, S. J. Polym. Sci. 1963, 1, 1079.
28. Gupta, A.; Liang, R.; Tsay, F.-D.; Moacanin, J. Macromolecules 1980, 13, 1696.
29. Shultz, A. R.; Frank, P.; Griffing, B. F.; Young, A. L. J. Polym. Sci., Polym. Phys. Ed. 1985, 23, 1749.
30. Forbes, M. D. E. Photochem. Photobiol. 1997, 65, 73.
31. Zundel, T.; Teyssie, P.; Jerome, R. Macromolecules 1998, 31, 2433.
32. Eckl, M.; Müller, H.; Strohriegl, P.; Beckmann, S.; Etzbach, K. H.; Eich, M.; Vydra, J. Macromol. Chem. Phys. 1995, 196, 315.