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Volumn 65, Issue 1, 1997, Pages 73-81

Time-resolved (CW) electron paramagnetic resonance spectroscopy: An overview of the technique and its use in organic photochemistry

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EID: 0031050581     PISSN: 00318655     EISSN: None     Source Type: Journal    
DOI: 10.1111/j.1751-1097.1997.tb01879.x     Document Type: Conference Paper
Times cited : (62)

References (45)
  • 1
    • 15444338799 scopus 로고
    • A new technique for the study of rapid free radical reactions
    • Cambridge Press
    • Piette, L. H. (1963) A new technique for the study of rapid free radical reactions. Sixth International Symposium on Free Radicals, Cambridge Press.
    • (1963) Sixth International Symposium on Free Radicals
    • Piette, L.H.1
  • 7
    • 0346562449 scopus 로고
    • EPR detection of the hydrated electron in liquid water
    • Avery, E. C., J. R. Remko and B. Smaller (1968) EPR detection of the hydrated electron in liquid water. J. Chem. Phys. 59, 951.
    • (1968) J. Chem. Phys. , vol.59 , pp. 951
    • Avery, E.C.1    Remko, J.R.2    Smaller, B.3
  • 8
    • 0000791125 scopus 로고
    • Time resolved electron spin resonance spectroscopy. III. Electron spin resonance emission from the hydrated electron. Possible evidence for reaction to the Triplet State
    • Fessenden, R. W. and N. C. Verma (1976) Time resolved electron spin resonance spectroscopy. III. Electron spin resonance emission from the hydrated electron. Possible evidence for reaction to the Triplet State. J. Am. Chem. Soc. 98, 243-244.
    • (1976) J. Am. Chem. Soc. , vol.98 , pp. 243-244
    • Fessenden, R.W.1    Verma, N.C.2
  • 9
    • 1442294959 scopus 로고
    • Time resolved ESR spectroscopy. IV. Detailed measurement and analysis of the ESR time profile
    • Verma, N. C. and R. W. Fessenden (1976) Time resolved ESR spectroscopy. IV. Detailed measurement and analysis of the ESR time profile. J. Chem. Phys. 65, 2139-2155.
    • (1976) J. Chem. Phys. , vol.65 , pp. 2139-2155
    • Verma, N.C.1    Fessenden, R.W.2
  • 10
    • 0011384102 scopus 로고
    • Submicrosecond time-resolved EPR in laser photolysis
    • Trifunac, A. D., M. C. Thurnauer and J. R. Norris (1978) Submicrosecond time-resolved EPR in laser photolysis. Chem. Phys. Lett. 57, 471-473.
    • (1978) Chem. Phys. Lett. , vol.57 , pp. 471-473
    • Trifunac, A.D.1    Thurnauer, M.C.2    Norris, J.R.3
  • 12
    • 11744352647 scopus 로고
    • Fourier transform-electron paramagnetic resonance study of the photochemical reaction of acetone with 2-propanol
    • Levstein, P. R. and H. van Willigen (1991) Fourier transform-electron paramagnetic resonance study of the photochemical reaction of acetone with 2-propanol. J. Chem. Phys. 95, 900-908.
    • (1991) J. Chem. Phys. , vol.95 , pp. 900-908
    • Levstein, P.R.1    Van Willigen, H.2
  • 13
    • 0011783356 scopus 로고
    • Fourier transform electron spin resonance
    • Edited by L. R. Kevan and M. K. Bowman, Wiley, New York
    • Bowman, M. K. (1990) Fourier transform electron spin resonance. In Modern Pulsed and Continuous-wave Electron Spin Resonance. (Edited by L. R. Kevan and M. K. Bowman), pp. 1-42. Wiley, New York.
    • (1990) Modern Pulsed and Continuous-wave Electron Spin Resonance , pp. 1-42
    • Bowman, M.K.1
  • 14
    • 0000245199 scopus 로고
    • Application of Fourier transform electron paramagnetic resonance in the study of photochemical reactions
    • van Willigen, H., P. R. Levstein and M. H. Ebersole (1993) Application of Fourier transform electron paramagnetic resonance in the study of photochemical reactions. Chem. Rev. 93, 173-198.
    • (1993) Chem. Rev. , vol.93 , pp. 173-198
    • Van Willigen, H.1    Levstein, P.R.2    Ebersole, M.H.3
  • 15
    • 0001110168 scopus 로고
    • Unusual chemically induced dynamic electron polarization of electrons produced by photoionization
    • Jeevarajan, A. S. and R. W. Fessenden (1992) Unusual chemically induced dynamic electron polarization of electrons produced by photoionization. J. Phys. Chem. 96, 1520-1523.
    • (1992) J. Phys. Chem. , vol.96 , pp. 1520-1523
    • Jeevarajan, A.S.1    Fessenden, R.W.2
  • 16
    • 0001719766 scopus 로고
    • Two-photon processes in ketone photochemistry observed by time-resolved ESR spectroscopy
    • Jent, F., H. Paul and H. Fischer (1988) Two-photon processes in ketone photochemistry observed by time-resolved ESR spectroscopy. Chem. Phys. Lett. 146, 315-319.
    • (1988) Chem. Phys. Lett. , vol.146 , pp. 315-319
    • Jent, F.1    Paul, H.2    Fischer, H.3
  • 17
    • 33845279570 scopus 로고
    • Flash photolysis electron spin resonance
    • McLauchlan, K. A. and D. G. Stevens (1988) Flash photolysis electron spin resonance. Acc. Chem. Res. 21, 54-59.
    • (1988) Acc. Chem. Res. , vol.21 , pp. 54-59
    • McLauchlan, K.A.1    Stevens, D.G.2
  • 19
    • 0000791745 scopus 로고
    • Synthesis of tetrafluoroethylene-based nonaqueous fluoropolymers in supercritical carbon dioxide
    • Romack, T. J., J. M. DeSimone and T. A. Treat (1995) Synthesis of tetrafluoroethylene-based nonaqueous fluoropolymers in supercritical carbon dioxide. Macromolecules 28, 8429-8431.
    • (1995) Macromolecules , vol.28 , pp. 8429-8431
    • Romack, T.J.1    DeSimone, J.M.2    Treat, T.A.3
  • 20
    • 33751385530 scopus 로고
    • Electron spin polarization in radical-triplet pairs. Size and dependence on diffusion
    • Goudsmit, G.-H., H. Paul and A. I. Shushin (1993) Electron spin polarization in radical-triplet pairs. Size and dependence on diffusion. J. Phys. Chem. 97, 13243-13249.
    • (1993) J. Phys. Chem. , vol.97 , pp. 13243-13249
    • Goudsmit, G.-H.1    Paul, H.2    Shushin, A.I.3
  • 21
    • 0001403994 scopus 로고
    • Memory of spin polarization in triplet-doublet systems
    • Imamura, T., O. Onitsuka and K. Obi (1986) Memory of spin polarization in triplet-doublet systems. J. Phys. Chem. 90, 6741-6744.
    • (1986) J. Phys. Chem. , vol.90 , pp. 6741-6744
    • Imamura, T.1    Onitsuka, O.2    Obi, K.3
  • 22
    • 0000715613 scopus 로고
    • Chemically induced dynamic electron polarization. II. A general theory for radicals produced by photochemical reactions of excited triplet carbonyl compounds
    • Wong, S. K., D. A. Hutchinson and J. K. S. Wan (1973) Chemically induced dynamic electron polarization. II. A general theory for radicals produced by photochemical reactions of excited triplet carbonyl compounds. J. Chem. Phys. 58, 985-989.
    • (1973) J. Chem. Phys. , vol.58 , pp. 985-989
    • Wong, S.K.1    Hutchinson, D.A.2    Wan, J.K.S.3
  • 23
    • 0001544572 scopus 로고
    • Dynamics of spin-polarized radical pairs at the solid/solution interface
    • Forbes, M. D. E., S. R. Ruberu and K. E. Dukes (1994) Dynamics of spin-polarized radical pairs at the solid/solution interface. J. Am. Chem. Soc. 116, 7299-7307.
    • (1994) J. Am. Chem. Soc. , vol.116 , pp. 7299-7307
    • Forbes, M.D.E.1    Ruberu, S.R.2    Dukes, K.E.3
  • 24
    • 0010800838 scopus 로고
    • Spinpolarized electron paramagnetic resonance spectra of radical pairs in micelles. Observation of electron spin-spin interactions
    • Closs, G. L., M. D. E. Forbes and J. R. Norris, Jr. (1987) Spinpolarized electron paramagnetic resonance spectra of radical pairs in micelles. Observation of electron spin-spin interactions. J. Phys. Chem. 91, 3592-3599.
    • (1987) J. Phys. Chem. , vol.91 , pp. 3592-3599
    • Closs, G.L.1    Forbes, M.D.E.2    Norris Jr., J.R.3
  • 26
    • 0029799661 scopus 로고    scopus 로고
    • Unusual dynamics of micellized radical pairs generated from photochemically active amphiphiles
    • Forbes, M. D. E., G. R. Schulz and N. I. Avdievich (1996) Unusual dynamics of micellized radical pairs generated from photochemically active amphiphiles. J. Am. Chem. Soc. 118, 10652-10653.
    • (1996) J. Am. Chem. Soc. , vol.118 , pp. 10652-10653
    • Forbes, M.D.E.1    Schulz, G.R.2    Avdievich, N.I.3
  • 27
    • 0000383462 scopus 로고
    • A time-resolved electron spin resonance and laser flash spectroscopy investigation of the photolysis of benzaldehyde and benzoin in homogeneous solvents and micellar solutions
    • Khudyakov, I. V., P. F. McGarry and N. J. Turro (1993) A time-resolved electron spin resonance and laser flash spectroscopy investigation of the photolysis of benzaldehyde and benzoin in homogeneous solvents and micellar solutions. J. Phys. Chem. 97, 13234-13242.
    • (1993) J. Phys. Chem. , vol.97 , pp. 13234-13242
    • Khudyakov, I.V.1    McGarry, P.F.2    Turro, N.J.3
  • 28
    • 0011744325 scopus 로고
    • Observation of medium chain length polymethylene biradicals in liquid solutions by time resolved EPR spectroscopy
    • Closs, G. L. and M. D. E. Forbes (1987) Observation of medium chain length polymethylene biradicals in liquid solutions by time resolved EPR spectroscopy. J. Am. Chem. Soc. 109, 6185-6187.
    • (1987) J. Am. Chem. Soc. , vol.109 , pp. 6185-6187
    • Closs, G.L.1    Forbes, M.D.E.2
  • 29
    • 0000964104 scopus 로고
    • EPR spectroscopy of electron spin polarized biradicals in liquid solutions. Technique, spectral simulation, scope and limitations
    • Closs, G. L. and M. D. E. Forbes (1991) EPR spectroscopy of electron spin polarized biradicals in liquid solutions. Technique, spectral simulation, scope and limitations. J. Phys. Chem. 95, 1924-1933.
    • (1991) J. Phys. Chem. , vol.95 , pp. 1924-1933
    • Closs, G.L.1    Forbes, M.D.E.2
  • 30
    • 0000706682 scopus 로고
    • Dynamic effects in spin-correlated radical pair theory: J modulation and a new look at the phenomenon of alternating line widths in the EPR spectra of flexible biradicals
    • Avdievich, N. I. and M. D. E. Forbes (1995) Dynamic effects in spin-correlated radical pair theory: J modulation and a new look at the phenomenon of alternating line widths in the EPR spectra of flexible biradicals. J. Phys. Chem. 99, 9660-9667.
    • (1995) J. Phys. Chem. , vol.99 , pp. 9660-9667
    • Avdievich, N.I.1    Forbes, M.D.E.2
  • 31
    • 15444354518 scopus 로고    scopus 로고
    • Strong modulation of the exchange interaction in a spin-polarized, aryl ether-linked 1,14-biradical
    • Avdievich, N. I. and M. D. E. Forbes (1996) Strong modulation of the exchange interaction in a spin-polarized, aryl ether-linked 1,14-biradical. J. Phys. Chem. 100, 1933-1995.
    • (1996) J. Phys. Chem. , vol.100 , pp. 1933-1995
    • Avdievich, N.I.1    Forbes, M.D.E.2
  • 32
    • 33751154550 scopus 로고    scopus 로고
    • Chain dynamics cause the disappearance of spin-correlated radical pair polarization in flexible biradicals
    • Forbes, M. D. E., N. I. Avdievich, G. R. Schulz and J. D. Ball (1996) Chain dynamics cause the disappearance of spin-correlated radical pair polarization in flexible biradicals. J. Phys. Chem. 100, 13887-13891.
    • (1996) J. Phys. Chem. , vol.100 , pp. 13887-13891
    • Forbes, M.D.E.1    Avdievich, N.I.2    Schulz, G.R.3    Ball, J.D.4
  • 33
    • 0027803518 scopus 로고
    • Acyclic diene metathesis (ADMET) polymerization: The synthesis of unsaturated polyketones
    • Wagener, K. B., J. T. Patton, M. D. E. Forbes, T. L. Myers and H. D. Maynard (1993) Acyclic diene metathesis (ADMET) polymerization: the synthesis of unsaturated polyketones. Polym. Int. 32, 411-415.
    • (1993) Polym. Int. , vol.32 , pp. 411-415
    • Wagener, K.B.1    Patton, J.T.2    Forbes, M.D.E.3    Myers, T.L.4    Maynard, H.D.5
  • 34
    • 15444351489 scopus 로고
    • Direct observation of polymeric radicals and biradicals by time-resolved EPR spectroscopy. Probing polymer chain dynamics and photodegradation at the same time
    • Forbes, M. D. E., T. L. Myers, J. T. Patton, K. B. Wagener and H. D. Maynard (1992) Direct observation of polymeric radicals and biradicals by time-resolved EPR spectroscopy. Probing polymer chain dynamics and photodegradation at the same time. Polym. Prep. (Am. Chem. Soc., Div. Polym. Chem.) 33, 883-884.
    • (1992) Polym. Prep. (Am. Chem. Soc., Div. Polym. Chem.) , vol.33 , pp. 883-884
    • Forbes, M.D.E.1    Myers, T.L.2    Patton, J.T.3    Wagener, K.B.4    Maynard, H.D.5
  • 35
    • 0000871117 scopus 로고
    • Quantitative EPR measurement of long distance electronic interactions in two geometric isomers of an unsaturated biradical
    • Forbes, M. D. E. and K. Bhagat (1993) Quantitative EPR measurement of long distance electronic interactions in two geometric isomers of an unsaturated biradical. J. Am. Chem. Soc. 115, 3382-3383.
    • (1993) J. Am. Chem. Soc. , vol.115 , pp. 3382-3383
    • Forbes, M.D.E.1    Bhagat, K.2
  • 36
    • 0038272818 scopus 로고
    • The effect of localized unsaturation on the scalar exchange coupling in flexible biradicals
    • Forbes, M. D. E. (1993) The effect of localized unsaturation on the scalar exchange coupling in flexible biradicals. J. Phys. Chem. 97, 3390-3395.
    • (1993) J. Phys. Chem. , vol.97 , pp. 3390-3395
    • Forbes, M.D.E.1
  • 37
    • 0029894940 scopus 로고    scopus 로고
    • In search of through-solvent electronic coupling in flexible biradicals
    • Forbes, M. D. E., J. D. Ball and N. I. Avdievich (1996) In search of through-solvent electronic coupling in flexible biradicals. J. Am. Chem. Soc. 118, 4707-4708.
    • (1996) J. Am. Chem. Soc. , vol.118 , pp. 4707-4708
    • Forbes, M.D.E.1    Ball, J.D.2    Avdievich, N.I.3
  • 38
    • 0000160664 scopus 로고
    • The temperature dependence of the exchange coupling in polymethylene biradicals. Conclusions regarding the mechanism of the coupling
    • Forbes, M. D. E., G. L. Closs, P. Calle and P. Gautam (1993) The temperature dependence of the exchange coupling in polymethylene biradicals. Conclusions regarding the mechanism of the coupling. J. Phys. Chem. 97, 3384-3389.
    • (1993) J. Phys. Chem. , vol.97 , pp. 3384-3389
    • Forbes, M.D.E.1    Closs, G.L.2    Calle, P.3    Gautam, P.4
  • 39
    • 0011744907 scopus 로고
    • Transient EPR spectroscopy of photoinduced spin states in rigid matrices
    • Edited by A. J. Hoff, Elsevier, New York
    • Stehlik, D., C. H. Bock and M. C. Thurnauer (1989) Transient EPR spectroscopy of photoinduced spin states in rigid matrices. In Advanced EPR: Applications in Biology and Biochemistry (Edited by A. J. Hoff), pp. 371-403. Elsevier, New York.
    • (1989) Advanced EPR: Applications in Biology and Biochemistry , pp. 371-403
    • Stehlik, D.1    Bock, C.H.2    Thurnauer, M.C.3
  • 40
    • 21844488512 scopus 로고
    • Time-resolved W-band (95 GHz) EPR spectroscopy of Zn-substituted reaction centers of Rhodobacter sphaeroides R-26
    • Prisner, T. F., A. van der Est, R. Bittl, W. Lubitz, D. Stehlik and K. Möbius (1995) Time-resolved W-band (95 GHz) EPR spectroscopy of Zn-substituted reaction centers of Rhodobacter sphaeroides R-26. Chem. Phys. 194, 361-370.
    • (1995) Chem. Phys. , vol.194 , pp. 361-370
    • Prisner, T.F.1    Van Der Est, A.2    Bittl, R.3    Lubitz, W.4    Stehlik, D.5    Möbius, K.6
  • 41
    • 0042965925 scopus 로고
    • A fast 35 GHz time-resolved EPR apparatus
    • Forbes, M. D. E. (1993) A fast 35 GHz time-resolved EPR apparatus. Rev. Sci. Instrum. 64, 397-402.
    • (1993) Rev. Sci. Instrum. , vol.64 , pp. 397-402
    • Forbes, M.D.E.1
  • 42
    • 84945049210 scopus 로고
    • Time resolved electron paramagnetic resonance spectroscopy in the Q-band microwave region. 2. Magnetic field effects on CIDEP in radicals, biradicals, and spin-correlated radical pairs
    • Forbes, M. D. E. (1993) Time resolved electron paramagnetic resonance spectroscopy in the Q-band microwave region. 2. Magnetic field effects on CIDEP in radicals, biradicals, and spin-correlated radical pairs. Z. Phys. Chem. 182, 63-76.
    • (1993) Z. Phys. Chem. , vol.182 , pp. 63-76
    • Forbes, M.D.E.1
  • 43
    • 0001553804 scopus 로고
    • Time resolved electron paramagnetic resonance spectroscopy in the Q-band microwave region
    • Forbes, M. D. E. (1992) Time resolved electron paramagnetic resonance spectroscopy in the Q-band microwave region. J. Phys. Chem. 96, 7836-7839.
    • (1992) J. Phys. Chem. , vol.96 , pp. 7836-7839
    • Forbes, M.D.E.1
  • 44
    • 0028378071 scopus 로고
    • Photodegradation of alternating p-butylstyrenyl and exonorbornyl-CO copolymers studied by multiple frequency time-resolved EPR spectroscopy
    • Forbes, M. D. E., J. C. Barborak, K. E. Dukes and S. R. Ruberu (1994) Photodegradation of alternating p-butylstyrenyl and exonorbornyl-CO copolymers studied by multiple frequency time-resolved EPR spectroscopy. Macromolecules 27, 1020-1026.
    • (1994) Macromolecules , vol.27 , pp. 1020-1026
    • Forbes, M.D.E.1    Barborak, J.C.2    Dukes, K.E.3    Ruberu, S.R.4
  • 45
    • 0030736596 scopus 로고    scopus 로고
    • Time-Resolved EPR study of a 1,9- flexible biradical dissolved in liquid Carbon Dioxide. Observation of a new spin relaxation phenomenon: Alternating intensities in spin-correlated radical pair spectra
    • In press
    • Avdievich, N. I., K. E. Dukes, M. D. E. Forbes, and J. M. DeSimone (1997) Time-Resolved EPR study of a 1,9-flexible biradical dissolved in liquid Carbon Dioxide. Observation of a new spin relaxation phenomenon: Alternating intensities in spin-correlated radical pair spectra. J. Phys. Chem. (In press)
    • (1997) J. Phys. Chem.
    • Avdievich, N.I.1    Dukes, K.E.2    Forbes, M.D.E.3    DeSimone, J.M.4


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