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16644393614
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note
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Although 1 and 2 contain thiocarbonyl groups, which could possibly compete with the pyridyl nitrogens in interacting with halogens and interhalogens, their donor ability is so low that it was impossible to determine the stability constant of N,N′-dimethylimidazolidine-4,5-dione-2-thione adduct with diiodine [29]
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16644365494
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note
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It is worth noting that in the case of the products obtained from the reactions between pyridyl donors and halogens or interhalogens, FT-IR spectroscopy is not of great help in investigating the nature of the compounds isolated in the solid state. In fact, whatever the reaction product (adduct or N-protonated donor balanced by halide or polyhalide anions), the MIR spectrum is very similar to that of the starting donor, the only difference being the presence of the NH stretching band, occurring under protonation. As far as the FIR region is regarded, much more information is gained from FT-Raman spectroscopy
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16644374515
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