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Volumn 11, Issue 1, 2005, Pages 152-159

On the gas-phase reactivity of complexed OH+ with halogenated alkanes

Author keywords

C H activation; Gas phase reactions; Oxidation; Peroxides; Proton affinities

Indexed keywords

GAS PHASE; GAS-PHASE REACTIVITY; PROTON TRANSFER; QUANTUM CHEMICAL CALCULATIONS;

EID: 19944429882     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200400699     Document Type: Article
Times cited : (6)

References (53)
  • 6
    • 0035794924 scopus 로고    scopus 로고
    • Å. M. Øiestad, A. C. Petersen, V. Bakken, J. Vedde, E. Uggerud, Angew. Chem. 2001, 113, 1345-1349; Angew. Chem. Int. Ed. 2001, 40, 1305-1309.
    • (2001) Angew. Chem. Int. Ed. , vol.40 , pp. 1305-1309
  • 8
    • 11244315024 scopus 로고    scopus 로고
    • note
    • In exothermic gas-phase reactions, the excess reaction enthalpy cannot be released into the surrounding medium as in solution. "Hot" intermediates release their internal energy by three different mechanisms, such as dissociation and transformation of the internal energy into translational energy, radiative processes, and at higher pressure by collisions.
  • 25
    • 0030766274 scopus 로고    scopus 로고
    • b) D. Feichtinger, D. A. Plattner, Angew. Chem. 1997, 109, 1796-1798; Angew. Chem. Int. Ed. Engl. 1997, 36, 1718-1719;
    • (1997) Angew. Chem. Int. Ed. Engl. , vol.36 , pp. 1718-1719
  • 28
    • 11244266978 scopus 로고    scopus 로고
    • note
    • -1 more basic than the oxygen atom.[34a] Picoline-N-oxide is most likely protonated on the oxygen atom although protonation on the nitrogen atom or pyridine ring cannot be excluded.
  • 32
    • 11244307984 scopus 로고    scopus 로고
    • note
    • m*//MP2/6-31G(d) for TS 5b/6b.
  • 35
    • 11244289062 scopus 로고    scopus 로고
    • note
    • + would react with alkanes by one-electron rather than by two-electron oxidation due to its high electron affinity of 13 eV.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.