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19944370041
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note
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5+ line broadening (6.5 kcal/mol) is well below what we would expect on the basis of the other data, the temperature-dependent behavior of the data was reproducible. The anomalously low result could arise from a difference in the ground state or transition state energetics or could be an artifact of the measurement. It is possible that the system is in the intermediate kinetic regime over a greater temperature range than expected but that curvature of the Eyring plot is masked by an unforeseen effect (such as an unexpected temperature dependence of the electronic relaxation time). If the latter case holds, then the value of the 25 °C rate constant we report would be low.
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19944401803
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note
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a sensitivity parameters (α) determined by linear regression for the two-parameter model described in eq 6.
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