Reductions by aquatitanium(II)

Dalton Transactions

Volumn , Issue 10, 2005, Pages 1781-1784

  Yang, Zhiyong ^a   Gould, Edwin S ^a  

^a KENT STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

LIGAND-TO-METAL BOND BREAKAGE; NITROSODISULFONATE ANIONS; REDOX CHEMISTS; TITANIUM WIRES;

BINARY MIXTURES; DECOMPOSITION; DIMERS; HYDROFLUORIC ACID; MOLECULAR STRUCTURE; NEGATIVE IONS; OXIDATION; PH EFFECTS; POSITIVE IONS; REDOX REACTIONS; REDUCTION; SPECTROPHOTOMETERS; STOICHIOMETRY;

TITANIUM;

BENZOQUINONE; BENZOQUINONE DERIVATIVE; BORIC ACID; CHLORANILIC ACID; COBALT; FREMY'S SALT; NITROSO DERIVATIVE; OXIDIZING AGENT; PENTAAMMINEAQUOCOBALT(III); QUATERNARY AMMONIUM DERIVATIVE; REDUCING AGENT; TITANIUM;

ARTICLE; CHEMISTRY; COMPARATIVE STUDY; KINETICS; OXIDATION REDUCTION REACTION; ULTRAVIOLET SPECTROPHOTOMETRY;

BENZOQUINONES; BORATES; COBALT; KINETICS; NITROSO COMPOUNDS; OXIDANTS; OXIDATION-REDUCTION; QUATERNARY AMMONIUM COMPOUNDS; REDUCING AGENTS; SPECTROPHOTOMETRY, ULTRAVIOLET; TITANIUM;

EID: 19544364899     PISSN: 14779226     EISSN: 14779234     Source Type: Journal    
DOI: 10.1039/b416975c     Document Type: Article

References (33)

1. Z. Yang and E. S. Gould, Dalton Trans., 2004, 3601.
2. U. Kolle and P. Kolle, Angew. Chem., Int. Ed., 2003, 42, 4540.
3. G. H. Forbes and I. F. Hall, J. Am. Chem. Soc., 1924, 46, 583.
4. J. W. Oliver and J. W. Ross, Jr., J. Am. Chem. Soc., 1963, 85, 2565.
5. H. Zimmer, D. C. Lankin and S. W. Horgan, Chem. Rev., 1971, 71, 229.
6. S. Yamada and R. Tsuchida, Bull Chem. Soc. Jpn., 1959, 32, 721.
7. H. Gehlen and J. Cermak, Z. Anorg. Allg. Chem., 1954, 275, 113.
8. E. S. Gould and H. Taube, J. Am. Chem. Soc., 1964, 86, 1318.
9. F. Basolo and R. K. Murmann, Inorg. Synth., 1953, 4, 171.
10. A. Haim and H. Taube, J. Am. Chem. Soc., 1963, 85, 495.
11. J. C. Bailar, Jr. and E. M. Jones, Inorg. Synth., 1939, 1, 7.
12. O. A. Babich and E. S. Gould, Inorg. Chem., 2000, 39, 4119.
13. B. A. Barshop, R. F. Wrenn and C. Frieden, Anal. Biochem., 1983, 130, 134.
14. -2.
15. A more complicated picture associated with reduction of the iodo complex, which exhibits contributions both first- and second order in Ti(II), is considered in a subsequent study.
16. D. A. Palmer, R. W. Ramette and R. E. Mesmer, J. Solution Chem., 1984, 13, 673.
17. C. E. Johnson and S. Winstein, J. Am. Chem. Soc., 1951, 73, 2601.
18. A. Adegite and J. F. Lyun, Inorg. Chem., 1979, 12, 3602.
19. See, for example, A. G. Lappin, Redox Mechanisms in Inorganic Chemistry, Ellis Harwood, New York, 1994, ch. 5.
20. Z. Yang and E. S. Gould, Dalton Trans., 2003, 2219.
21. R. M. Smith and A. E. Martell, Critical Stability Constants, vol. 3, Plenum, New York, 1977, p. 282.
22. See, for example: (a) A. H. Martin and E. S. Gould, Inorg. Chem., 1975, 14, 873;
23. A.H. Martin and E.S. Gould, Inorg. Chem., 1976, 15, 1934;
24. (b) J. P. Birk, Inorg. Chem., 1975, 14, 1724.
25. F. Basolo and R. G. Pearson, Mechanisms of Inorganic Reactions, 2nd edn., Wiley, New York, 1968, Chaps. 1 and 6, Tables 1-9 and 6-4.
26. (a) J. P. Candlin and J. Halpern, Inorg. Chem., 1965, 4, 766;
27. (b) M.-Y. Wu, S. J. Paton, Y.-T. Fanchiang, E. Gelerinter and E. S. Gould, Inorg. Chem., 1978, 17, 326.
28. S. K. Chandra and E. S. Gould, Inorg. Chem., 1996, 35, 3159.
29. Ti(III) is included here as its OH-bound cationic form in view of the evidence that Co(III)-Ti(III) reactions proceed predominanantly through the deprotonated reductant.
30. A. Haim, Inorg. Chem., 1968, 7, 1475.
31. W. J. James and J. W. Johnson, in Standard Potentials in Aqueous Solution, eds. A. J. Bard, R. Parsons and J. Jordan, Marcel Dekker, New York, 1985, ch. 18.
32. R. A. Marcus, Annu. Rev. Phys. Chem., 1964, 15, 155.
33. M. C. Ghosh and E. S. Gould, J. Am. Chem. Soc., 1993, 115, 3167.