Electron transfer. 129. Copper Catalysis in the thiol reduction of oxime-bound nickel(IV)

Inorganic Chemistry

Volumn 35, Issue 11, 1996, Pages 3159-3162

  Mandal, Subrata ^a   Bose, R N ^a   Reed, J W ^a   Gould, E S ^a  

^a KENT STATE UNIVERSITY   (United States)

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EID: 0347165213     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic951520b     Document Type: Article

References (26)

1. Sponsorship of this work by the National Science Foundation (Grant 9314113) is gratefully acknowledged.
2. Reviews: (a) Sacconi, I.; Mani, F.; Bencini, A. In Comprehensive Coordination Chemistry; Wilkinson, G., Ed.: Pergamon: Oxford, U.K., 1987: Vol. 5, pp 287-300. (b) Haines, R. J.; McAuley. A. Coord, Chem. Rev. 1981, 39, 77. (c) Nag, K.; Chakravorty, A. Coord. Chem. Rev. 1980, 33, 87.
3. Reviews: (a) Sacconi, I.; Mani, F.; Bencini, A. In Comprehensive Coordination Chemistry; Wilkinson, G., Ed.: Pergamon: Oxford, U.K., 1987: Vol. 5, pp 287-300. (b) Haines, R. J.; McAuley. A. Coord, Chem. Rev. 1981, 39, 77. (c) Nag, K.; Chakravorty, A. Coord. Chem. Rev. 1980, 33, 87.
4. Reviews: (a) Sacconi, I.; Mani, F.; Bencini, A. In Comprehensive Coordination Chemistry; Wilkinson, G., Ed.: Pergamon: Oxford, U.K., 1987: Vol. 5, pp 287-300. (b) Haines, R. J.; McAuley. A. Coord, Chem. Rev. 1981, 39, 77. (c) Nag, K.; Chakravorty, A. Coord. Chem. Rev. 1980, 33, 87.
5. See, for example: (a) Lancaster, J. R., Jr. Science 1982, 216, 1324. (b) The Bioinorganic Chemistry of Nickel; Lancaster, J. R., Jr., Ed.; VCH Publishers: New York, 1988; Chapters 2-4. (c) Kruger, H.-J.; Holm, R. H. J. Am. Chem. Soc. 1990, 112, 2955.
6. See, for example: (a) Lancaster, J. R., Jr. Science 1982, 216, 1324. (b) The Bioinorganic Chemistry of Nickel; Lancaster, J. R., Jr., Ed.; VCH Publishers: New York, 1988; Chapters 2-4. (c) Kruger, H.-J.; Holm, R. H. J. Am. Chem. Soc. 1990, 112, 2955.
7. See, for example: (a) Lancaster, J. R., Jr. Science 1982, 216, 1324. (b) The Bioinorganic Chemistry of Nickel; Lancaster, J. R., Jr., Ed.; VCH Publishers: New York, 1988; Chapters 2-4. (c) Kruger, H.-J.; Holm, R. H. J. Am. Chem. Soc. 1990, 112, 2955.
8. See. for example: (a) Macartney, D. H.; McAuley, A.; Olubyide, O. Inorg. Chem. 1985, 24, 307. (b) Lappin, A. G.; Martone, D. P.; Osvath, P.; Marusak, R. A. Inorg. Chem. 1988, 27, 1863. (c) Bhattacharya, S.; Ali, M.; Gangopadhyay, S.; Banerjee, P. J. Chem. Soc., Dalton Trans. 1994, 3733.
9. See. for example: (a) Macartney, D. H.; McAuley, A.; Olubyide, O. Inorg. Chem. 1985, 24, 307. (b) Lappin, A. G.; Martone, D. P.; Osvath, P.; Marusak, R. A. Inorg. Chem. 1988, 27, 1863. (c) Bhattacharya, S.; Ali, M.; Gangopadhyay, S.; Banerjee, P. J. Chem. Soc., Dalton Trans. 1994, 3733.
10. See. for example: (a) Macartney, D. H.; McAuley, A.; Olubyide, O. Inorg. Chem. 1985, 24, 307. (b) Lappin, A. G.; Martone, D. P.; Osvath, P.; Marusak, R. A. Inorg. Chem. 1988, 27, 1863. (c) Bhattacharya, S.; Ali, M.; Gangopadhyay, S.; Banerjee, P. J. Chem. Soc., Dalton Trans. 1994, 3733.
11. See, for example: Ghosh, M. C.; Gelennter, E.; Gould, E. S. Inorg. Chem. 1991, 30, 1039.
12. Mandal, S.; Gould, E. S. Inorg. Chem. 1995, 34, 3993.
13. (a) Baucom, E. I.; Drago, R. S. J. Am. Chem. Soc. 1971, 93, 6469.
14. (b) Sproul, G.; Stucky, G. D. Inorg. Chem. 1973, 12, 2898.
15. Saha, S K.; Ghosh, M C.; Gould, E. S. Inorg. Chem. 1992, 31, 5439
16. Reductions of the same Ni(IV) complex with other thiols yielded less satisfactory kinetic pictures. Reductions with cysteine were catalyzed by both Cu(II) and Fe(III), but replicate runs were not reproducible Reductions with mercaptoacetic acid, as catalyzed by Cu(II), were rapid and exhibited nearly exponential profiles near pH 4.5. but the resulting data at various reagent concentrations did not establish a meaningful rate law.
17. See, for example: (a) Lappin, A. G., McAuley, A. J. Chem. Soc., Dalton Trans. 1978, 1606. (b) Davis, F. J.; Gilbert, B. C.; Norman, R. O. C ; Symons, M. C. R. J. Chem. Soc., Perkin Trans. 2 1983, 1763.
18. See, for example: (a) Lappin, A. G., McAuley, A. J. Chem. Soc., Dalton Trans. 1978, 1606. (b) Davis, F. J.; Gilbert, B. C.; Norman, R. O. C ; Symons, M. C. R. J. Chem. Soc., Perkin Trans. 2 1983, 1763.
19. Barshop, B. A.; Wrenn, R. F.; Frieden, C. Anal. Biochem. 1983, 130, 134. The original KINSIM program, for which we thank Dr. Carl Frieden, was developed for use on a VAX computer system. This was modified, using FORTRAN-77, to a "fixed-length" format and executed on an IBM 308ID system.
20. -1.
21. (a) Graham, D. M.; Mieville, R. L.; Pallen, R. H.; Sivertz, C. Can. J. Chem. 1964, 42, 2250.
22. (b) Burshtein, A. I.; Khudyakov, I. V.; Yakobsen, B. I. Prog. React. Kinet. 1984, 13, 221.
23. See, for example, Espenson, J. H. Chemical Kinetics and Reaction Mechanisms; McGraw-Hill: New York. 1981; p 169.
24. For evidence that a second route may be available for the destruction of the radical RSH, see, for example: Asmus, K.-D. Methods Enzymol. 1990, 186, 168. Such an alternate path would come into play after the rate-determining steps in the suggested sequence and should not affect the net kinetic pattern.
25. Ghosh, S. K.; Saha, S. K.; Ghosh, M C.; Bose, R. N.; Reed, J. W.; Gould, E. S. Inorg. Chem. 1992, 31, 3358
26. Ghosh, S. P.; Saha, S. K.; Bose, R N ; Reed, J. W ; Ghosh, M. C.; Gould, E. S Inorg Chem. 1993, 32, 2261.