A one-pot method to prepare the carbene complex [TpMe2,ClRhCl2(CHNiPr2] from [TpMe2,ClRh(CO)2], CHCl3, and NHiPr2

Journal of Organometallic Chemistry

Volumn 689, Issue 10, 2004, Pages 1763-1765

  Teuma, Emmanuelle ^a   Malbosc, François ^a   Etienne, Michel ^b   Daran, Jean Claude ^b   Kalck, Philippe ^a  

^a UNIVERSITÉ DE TOULOUSE   (France)

^b LCC LABORATOIRE DE CHIMIE DE COORDINATION   (France)

Author keywords

C Cl activation; Carbene; Hydrotris(pyrazolyl)borate; Rhodium

Indexed keywords

CARBENE; CARBON; CHLORIDE; CHLOROFORM; DIISOPROPYLAMINE;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; COMPLEX FORMATION; CRYSTAL STRUCTURE; OXIDATION; X RAY DIFFRACTION;

EID: 1942439928     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2004.02.030     Document Type: Article

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12. We thank one referee for suggesting this second mechanism