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The length of the Ni(II) complex from 4′ to 4′ carbon atoms (parallel to the pseudo twofold axis) is 9.39 Ã... compared to 9.35 Ã... for the Ru(II) complex. Transverse to this, the distances across the two terpy ligands (4 to 4″ carbon atoms) are 9.38 and 9.39 Ã... while the corresponding dimensions for the Ru(II) complex are 9.29 and 9.30 Ã.... The Nâ€"N′â€"N″ bite angles for the Ni(II) complex are 105.7 and 106.1° while the corresponding bite angles for the Ru(II) complex are 103.7 and 104.5°.
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