Synthesis, structure, and magnetism of a novel alkoxide bridged nonacopper(II) (Cu9O12) [3 x 3] square grid generated by a strict self-assembly process

Angewandte Chemie - International Edition

Volumn 39, Issue 17, 2000, Pages 3114-3117

  Zhao, Liang ^a   Xu, Zhiqiang ^a   Thompson, Laurence K ^a   Heath, Sarah L ^b   Miller, David O ^a   Ohba, Masaaki ^c  

^a MEMORIAL UNIVERSITY OF NEWFOUNDLAND   (Canada)

^b UNIVERSITY OF YORK   (United Kingdom)

^c KYUSHU UNIVERSITY   (Japan)

Author keywords

Coordination chemistry; Copper; Magnetic properties; Supramolecular chemistry

Indexed keywords

COPPER DERIVATIVE;

ARTICLE; BINDING SITE; CHEMICAL STRUCTURE; CONFORMATION; GEOMETRY; MAGNETISM; SYNTHESIS;

EID: 0034283383     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3773(20000901)39:17<3114::AID-ANIE3114>3.0.CO;2-Z     Document Type: Article

References (14)

1. M.-T. Youinou, N. Rahmouni, J. Fischer, J. A. Osborn, Angew. Chem. 1992, 104, 771; Angew. Chem. Int. Ed. Engl. 1992, 31, 733-735.
2. M.-T. Youinou, N. Rahmouni, J. Fischer, J. A. Osborn, Angew. Chem. 1992, 104, 771; Angew. Chem. Int. Ed. Engl. 1992, 31, 733-735.
3. G. S. Hannan, D. Volkmer, U. S. Schubert, J-M. Lehn, G. Baum, D. Fenske, Angew. Chem. 1997, 109, 1929-1931: Angew. Chem. Int. Ed. Engl. 1997, 36, 1842-1844.
4. G. S. Hannan, D. Volkmer, U. S. Schubert, J-M. Lehn, G. Baum, D. Fenske, Angew. Chem. 1997, 109, 1929-1931: Angew. Chem. Int. Ed. Engl. 1997, 36, 1842-1844.
5. P. N. W. Baxter, J.-M. Lehn, J. Fischer, M.-T. Youinou, Angew. Chem. 1994, 106, 2432; Angew. Chem. Int. Ed. Engl. 1994, 33, 2284-2287.
6. P. N. W. Baxter, J.-M. Lehn, J. Fischer, M.-T. Youinou, Angew. Chem. 1994, 106, 2432; Angew. Chem. Int. Ed. Engl. 1994, 33, 2284-2287.
7. O. Waldmann, J. Hassmann, P. Müller, G. S. Hannan, D. Volkmer, U. S. Schubert, J.-M. Lehn, Phys. Rev. Lett. 1997, 78, 3390-3393.
8. C. J. Matthews, K. Avery, Z. Xu, L. K. Thompson, L. Zhao, D. O. Miller, K. Biradha, K. Poirier, M. J. Zaworotko, C. Wilson, A. E. Goeta, J. A. K. Howard. Inorg. Chem. 1999, 38, 5266-5276.
9. C. J. Matthews, Z. Xu, S. K. Mandal, L. K. Thompson, K. Biradha, K. Poirier, M. J. Zaworotko, Chem. Commun. 1999, 347-348.
10. L. Zhao, L. K. Thompson, S. R. Parsons, C. J. Matthews, unpublished results.
11. int = 0.0922), for 20 in the range 1.56 to 50.0 (GOF = 0.900). Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-140825. Copies of the data can be obtained free of charge on application to CCDC. 12 Union Road. Cambridge CB2 1EZ, UK (fax: (+ 44) 1223-336-033; e-mail: deposit@ ccdc.cam.ac.uk).
12. L. Zhao, C. J. Matthews, L. K. Thompson, S. L. Heath, Chem. Commun. 2000, 265-266.
13. Variable temperature magnetic measurements were carried out in the range 2-300 K using a SOUID magnetometer (Quantum Design MPMS5S) in fields of 0.1-5.0 T. Background corrections for the sample holder and diamagnetic portions of the complex were applied.
14. A.M. Garcia, F. J. Romero-Salguero, D.M. Bassani, J.-M. Lehn, G. Baum, D. Fenske, Chem. Eur. J. 1999, 5, 1803-1808.